Removal of cadmium from water by CNT–PAC composite: effect of functionalization

Cadmium (Cd2þ) is one of the toxic heavy metals that is frequently used in many industrial products. The wastewater from these industries and their products contains residual cadmium that are di±cult to be removed economically from the e®luent. Carbon nanotubes (CNTs) were synthesized in several...

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Main Authors: AlSaadi, Mohammed A., Mamun, Abdullah Al, Alam, Md Zahangir, Amosa, Mutiu Kolade, Atieh, Muataz Ali
Format: Article
Language:English
English
English
Published: World Scientic Publishing Company 2016
Subjects:
Online Access:http://irep.iium.edu.my/46622/
http://irep.iium.edu.my/46622/1/Published_Paper_Nano.pdf
http://irep.iium.edu.my/46622/4/46622_Removal%20of%20cadmium%20from%20water_SCOPUS.pdf
http://irep.iium.edu.my/46622/5/46622_Removal%20of%20cadmium%20from%20water_WOS.pdf
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author AlSaadi, Mohammed A.
Mamun, Abdullah Al
Alam, Md Zahangir
Amosa, Mutiu Kolade
Atieh, Muataz Ali
author_facet AlSaadi, Mohammed A.
Mamun, Abdullah Al
Alam, Md Zahangir
Amosa, Mutiu Kolade
Atieh, Muataz Ali
author_sort AlSaadi, Mohammed A.
building IIUM Repository
collection Online Access
description Cadmium (Cd2þ) is one of the toxic heavy metals that is frequently used in many industrial products. The wastewater from these industries and their products contains residual cadmium that are di±cult to be removed economically from the e®luent. Carbon nanotubes (CNTs) were synthesized in several batches and tested for their removal e±cacy with regards to cadmium removal from synthetic wastewater. Fixed catalyst chemical vapor deposition (FCCVD) reactor system was fabricated in the laboratory for the synthesis of CNTs on the powdered activated carbons (PACs). The PACs were impregnated with Fe3þ catalysts, and growth parameters such as, the reaction time, gas °ow rates and reaction temperature were optimized. The sorption capacity of the raw CNT–PAC was not satisfactory until the sorbents were functionalized which eventually led to high adsorption capacities. The surface properties of CNT–PAC were modi¯ed by oxidative functionalization using two di®erent methods: sonication with KMnO4 and re°uxing with HNO3 at 140�C. KMnO4-treated CNT–PAC exhibited the highest sorption capacity for cadmium uptake which increased from 4.77 mg/g (untreated CNT–PAC) to 11.16 mg/g; resulting in Cd2þ removal e±ciency from 38.87% to 98.35%.
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language English
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publishDate 2016
publisher World Scientic Publishing Company
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spelling iium-466222017-10-21T11:24:40Z http://irep.iium.edu.my/46622/ Removal of cadmium from water by CNT–PAC composite: effect of functionalization AlSaadi, Mohammed A. Mamun, Abdullah Al Alam, Md Zahangir Amosa, Mutiu Kolade Atieh, Muataz Ali TD169 Environmental protection Cadmium (Cd2þ) is one of the toxic heavy metals that is frequently used in many industrial products. The wastewater from these industries and their products contains residual cadmium that are di±cult to be removed economically from the e®luent. Carbon nanotubes (CNTs) were synthesized in several batches and tested for their removal e±cacy with regards to cadmium removal from synthetic wastewater. Fixed catalyst chemical vapor deposition (FCCVD) reactor system was fabricated in the laboratory for the synthesis of CNTs on the powdered activated carbons (PACs). The PACs were impregnated with Fe3þ catalysts, and growth parameters such as, the reaction time, gas °ow rates and reaction temperature were optimized. The sorption capacity of the raw CNT–PAC was not satisfactory until the sorbents were functionalized which eventually led to high adsorption capacities. The surface properties of CNT–PAC were modi¯ed by oxidative functionalization using two di®erent methods: sonication with KMnO4 and re°uxing with HNO3 at 140�C. KMnO4-treated CNT–PAC exhibited the highest sorption capacity for cadmium uptake which increased from 4.77 mg/g (untreated CNT–PAC) to 11.16 mg/g; resulting in Cd2þ removal e±ciency from 38.87% to 98.35%. World Scientic Publishing Company 2016-01-01 Article PeerReviewed application/pdf en http://irep.iium.edu.my/46622/1/Published_Paper_Nano.pdf application/pdf en http://irep.iium.edu.my/46622/4/46622_Removal%20of%20cadmium%20from%20water_SCOPUS.pdf application/pdf en http://irep.iium.edu.my/46622/5/46622_Removal%20of%20cadmium%20from%20water_WOS.pdf AlSaadi, Mohammed A. and Mamun, Abdullah Al and Alam, Md Zahangir and Amosa, Mutiu Kolade and Atieh, Muataz Ali (2016) Removal of cadmium from water by CNT–PAC composite: effect of functionalization. NANO: Brief Reports and Reviews, 11 (1). 1650011-1-1650011-7. ISSN 1793-2920 http://www.worldscientific.com/worldscinet/nano 10.1142/S1793292016500119
spellingShingle TD169 Environmental protection
AlSaadi, Mohammed A.
Mamun, Abdullah Al
Alam, Md Zahangir
Amosa, Mutiu Kolade
Atieh, Muataz Ali
Removal of cadmium from water by CNT–PAC composite: effect of functionalization
title Removal of cadmium from water by CNT–PAC composite: effect of functionalization
title_full Removal of cadmium from water by CNT–PAC composite: effect of functionalization
title_fullStr Removal of cadmium from water by CNT–PAC composite: effect of functionalization
title_full_unstemmed Removal of cadmium from water by CNT–PAC composite: effect of functionalization
title_short Removal of cadmium from water by CNT–PAC composite: effect of functionalization
title_sort removal of cadmium from water by cnt–pac composite: effect of functionalization
topic TD169 Environmental protection
url http://irep.iium.edu.my/46622/
http://irep.iium.edu.my/46622/
http://irep.iium.edu.my/46622/
http://irep.iium.edu.my/46622/1/Published_Paper_Nano.pdf
http://irep.iium.edu.my/46622/4/46622_Removal%20of%20cadmium%20from%20water_SCOPUS.pdf
http://irep.iium.edu.my/46622/5/46622_Removal%20of%20cadmium%20from%20water_WOS.pdf