Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes
Sodium morpholine-4-carbodithioate and four metal complexes were synthesized and characterized using various physico-chemical techniques. The ligand behaved as a uninegatively charged bidentate ligands upon complexation with metal ions with the general formula of Ma(SS)2 and Mb(SS)3, where Ma is Cu(...
| Main Authors: | , , |
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| Format: | Proceeding Paper |
| Language: | English |
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2015
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| Online Access: | http://irep.iium.edu.my/46445/ http://irep.iium.edu.my/46445/1/46445.pdf |
| _version_ | 1848782971084996608 |
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| author | How, Fiona Ni Foong Ahmad, J. Abdul Halim, S. Nadiah |
| author_facet | How, Fiona Ni Foong Ahmad, J. Abdul Halim, S. Nadiah |
| author_sort | How, Fiona Ni Foong |
| building | IIUM Repository |
| collection | Online Access |
| description | Sodium morpholine-4-carbodithioate and four metal complexes were synthesized and characterized using various physico-chemical techniques. The ligand behaved as a uninegatively charged bidentate ligands upon complexation with metal ions with the general formula of Ma(SS)2 and Mb(SS)3, where Ma is Cu(II) and Ni(II) and Mb is Co(III) and Fe(III). All the complexes have crystallographic data for structural comparison. Crystal structure of Iron and cobalt complexes existed in an octahedral coordination geometry with trapped lattice solvent. Nickel and copper complexes crystallized in square planar coordination geometry with no trapped solvent. The PXRD of all the complexes showed that the calculated PXRD data are coincide from the crystal structures of all the metal complexes. |
| first_indexed | 2025-11-14T16:13:56Z |
| format | Proceeding Paper |
| id | iium-46445 |
| institution | International Islamic University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T16:13:56Z |
| publishDate | 2015 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | iium-464452016-04-13T04:16:54Z http://irep.iium.edu.my/46445/ Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes How, Fiona Ni Foong Ahmad, J. Abdul Halim, S. Nadiah QD Chemistry Sodium morpholine-4-carbodithioate and four metal complexes were synthesized and characterized using various physico-chemical techniques. The ligand behaved as a uninegatively charged bidentate ligands upon complexation with metal ions with the general formula of Ma(SS)2 and Mb(SS)3, where Ma is Cu(II) and Ni(II) and Mb is Co(III) and Fe(III). All the complexes have crystallographic data for structural comparison. Crystal structure of Iron and cobalt complexes existed in an octahedral coordination geometry with trapped lattice solvent. Nickel and copper complexes crystallized in square planar coordination geometry with no trapped solvent. The PXRD of all the complexes showed that the calculated PXRD data are coincide from the crystal structures of all the metal complexes. 2015 Proceeding Paper NonPeerReviewed application/pdf en http://irep.iium.edu.my/46445/1/46445.pdf How, Fiona Ni Foong and Ahmad, J. and Abdul Halim, S. Nadiah (2015) Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes. In: 28th Regional Symposium Malaysian Analytical Sciences (SKAm28), 17-20 August 2015, Weil Hotel, Ipoh, Perak. (Unpublished) http://www.rgscnet.com/news_content.php?id=8 |
| spellingShingle | QD Chemistry How, Fiona Ni Foong Ahmad, J. Abdul Halim, S. Nadiah Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes |
| title | Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes |
| title_full | Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes |
| title_fullStr | Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes |
| title_full_unstemmed | Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes |
| title_short | Synthesis, characterization and structural studies of sodium morpholine-4-Carbodithioate and its metal complexes |
| title_sort | synthesis, characterization and structural studies of sodium morpholine-4-carbodithioate and its metal complexes |
| topic | QD Chemistry |
| url | http://irep.iium.edu.my/46445/ http://irep.iium.edu.my/46445/ http://irep.iium.edu.my/46445/1/46445.pdf |