Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine

Six new 2-halobenzoylthiourea compounds bearing α- and β-alanine have been successfully synthesized and characterized using CHNS microelemental analysis and spectroscopic methods including FTIR, UV-Vis and NMR. Microelemental analysis data of the compounds were in agreement with the theoretical valu...

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Main Authors: Ngah, Nurziana, Mohamed, Nor Azanita, Darnis, Deny Susanti
Format: Article
Language:English
English
English
Published: Chiang Mai University 2016
Subjects:
Online Access:http://irep.iium.edu.my/46121/
http://irep.iium.edu.my/46121/4/16-03-22-d490d.pdf
http://irep.iium.edu.my/46121/7/46121_Synthesis%2C%20Characterization%20and%20Antioxidant%20Activity%20of%202-Halobenzoyl_Scopus.pdf
http://irep.iium.edu.my/46121/13/46121_Synthesis%2C%20characterization%20and%20antioxidant%20activity_wos.pdf
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author Ngah, Nurziana
Mohamed, Nor Azanita
Darnis, Deny Susanti
author_facet Ngah, Nurziana
Mohamed, Nor Azanita
Darnis, Deny Susanti
author_sort Ngah, Nurziana
building IIUM Repository
collection Online Access
description Six new 2-halobenzoylthiourea compounds bearing α- and β-alanine have been successfully synthesized and characterized using CHNS microelemental analysis and spectroscopic methods including FTIR, UV-Vis and NMR. Microelemental analysis data of the compounds were in agreement with the theoretical values. The FTIR spectra showed the presence of important bands of the compounds while the 1 H-NMR and 13C-NMR exhibited the expected chemical shifts. The compounds exerted weak antioxidant activity in DPPH scavenging test and moderate to good activity in β-carotene bleaching test. The inclusion of halogen atoms has facilitated the released of hydrogen atoms and introduction of α- and β-alanine have increased the β-carotene bleaching and DPPH scavenging activities of the compounds.
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publishDate 2016
publisher Chiang Mai University
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spelling iium-461212017-10-12T05:22:53Z http://irep.iium.edu.my/46121/ Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine Ngah, Nurziana Mohamed, Nor Azanita Darnis, Deny Susanti QD Chemistry Six new 2-halobenzoylthiourea compounds bearing α- and β-alanine have been successfully synthesized and characterized using CHNS microelemental analysis and spectroscopic methods including FTIR, UV-Vis and NMR. Microelemental analysis data of the compounds were in agreement with the theoretical values. The FTIR spectra showed the presence of important bands of the compounds while the 1 H-NMR and 13C-NMR exhibited the expected chemical shifts. The compounds exerted weak antioxidant activity in DPPH scavenging test and moderate to good activity in β-carotene bleaching test. The inclusion of halogen atoms has facilitated the released of hydrogen atoms and introduction of α- and β-alanine have increased the β-carotene bleaching and DPPH scavenging activities of the compounds. Chiang Mai University 2016 Article PeerReviewed application/pdf en http://irep.iium.edu.my/46121/4/16-03-22-d490d.pdf application/pdf en http://irep.iium.edu.my/46121/7/46121_Synthesis%2C%20Characterization%20and%20Antioxidant%20Activity%20of%202-Halobenzoyl_Scopus.pdf application/pdf en http://irep.iium.edu.my/46121/13/46121_Synthesis%2C%20characterization%20and%20antioxidant%20activity_wos.pdf Ngah, Nurziana and Mohamed, Nor Azanita and Darnis, Deny Susanti (2016) Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine. Chiang Mai Journal of Science, 43 (3). pp. 577-583. ISSN 0125-2526 http://it.science.cmu.ac.th/ejournal/journalDetail.php?journal_id=6816
spellingShingle QD Chemistry
Ngah, Nurziana
Mohamed, Nor Azanita
Darnis, Deny Susanti
Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine
title Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine
title_full Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine
title_fullStr Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine
title_full_unstemmed Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine
title_short Synthesis, Characterization and Antioxidant Activity of 2-Halobenzoyl Thiourea Bearing α- and β-alanine
title_sort synthesis, characterization and antioxidant activity of 2-halobenzoyl thiourea bearing α- and β-alanine
topic QD Chemistry
url http://irep.iium.edu.my/46121/
http://irep.iium.edu.my/46121/
http://irep.iium.edu.my/46121/4/16-03-22-d490d.pdf
http://irep.iium.edu.my/46121/7/46121_Synthesis%2C%20Characterization%20and%20Antioxidant%20Activity%20of%202-Halobenzoyl_Scopus.pdf
http://irep.iium.edu.my/46121/13/46121_Synthesis%2C%20characterization%20and%20antioxidant%20activity_wos.pdf