Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables

Development and validation of an LC-MS/MS method suitable for the simultaneous quantification of phenolic acids and flavonoids is described. Analytes were separated on a C6-phenyl column, analysed using negative ion APCI selected reaction monitoring. The method is capable of analysing 14 compounds...

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Main Authors: Haron, Normah, Arcot, Jayashree, Bucknall, Martin
Format: Proceeding Paper
Language:English
Published: 2015
Subjects:
Online Access:http://irep.iium.edu.my/45944/
http://irep.iium.edu.my/45944/4/45944.pdf
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author Haron, Normah
Arcot, Jayashree
Bucknall, Martin
author_facet Haron, Normah
Arcot, Jayashree
Bucknall, Martin
author_sort Haron, Normah
building IIUM Repository
collection Online Access
description Development and validation of an LC-MS/MS method suitable for the simultaneous quantification of phenolic acids and flavonoids is described. Analytes were separated on a C6-phenyl column, analysed using negative ion APCI selected reaction monitoring. The method is capable of analysing 14 compounds (9 phenolic acids and 5 flavonoids) in 85 minutes and uses deuterium-labelled 4-hydroxy-3-methoxy-d3-cinnamic acid (ferulic acid-d3) and 13C15-quercetin as internal standards. The results demonstrated that the method developed was reliable, specific and robust. Thus the method was successfully applied to analyse phenolic compounds in 18 different types of traditional Malaysian vegetables (both raw and processed) with 3 different fractions of phenolic acids. Gallic, ferulic, vanillic and caffeic acids were the most dominant phenolic acids, while quercetin, apigenin, kaempferol and luteolin were the predominant flavonoids in the samples studied.
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institution International Islamic University Malaysia
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language English
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spelling iium-459442017-12-05T08:03:36Z http://irep.iium.edu.my/45944/ Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables Haron, Normah Arcot, Jayashree Bucknall, Martin Q Science (General) S Agriculture (General) Development and validation of an LC-MS/MS method suitable for the simultaneous quantification of phenolic acids and flavonoids is described. Analytes were separated on a C6-phenyl column, analysed using negative ion APCI selected reaction monitoring. The method is capable of analysing 14 compounds (9 phenolic acids and 5 flavonoids) in 85 minutes and uses deuterium-labelled 4-hydroxy-3-methoxy-d3-cinnamic acid (ferulic acid-d3) and 13C15-quercetin as internal standards. The results demonstrated that the method developed was reliable, specific and robust. Thus the method was successfully applied to analyse phenolic compounds in 18 different types of traditional Malaysian vegetables (both raw and processed) with 3 different fractions of phenolic acids. Gallic, ferulic, vanillic and caffeic acids were the most dominant phenolic acids, while quercetin, apigenin, kaempferol and luteolin were the predominant flavonoids in the samples studied. 2015-11-15 Proceeding Paper NonPeerReviewed application/pdf en http://irep.iium.edu.my/45944/4/45944.pdf Haron, Normah and Arcot, Jayashree and Bucknall, Martin (2015) Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables. In: Asian Congress on Biotechnology 2015, 15th-19th November 2015, Kuala Lumpur. (Unpublished)
spellingShingle Q Science (General)
S Agriculture (General)
Haron, Normah
Arcot, Jayashree
Bucknall, Martin
Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables
title Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables
title_full Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables
title_fullStr Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables
title_full_unstemmed Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables
title_short Development of LC/MS-MS method for analysis of polyphenols in Malaysian traditional vegetables
title_sort development of lc/ms-ms method for analysis of polyphenols in malaysian traditional vegetables
topic Q Science (General)
S Agriculture (General)
url http://irep.iium.edu.my/45944/
http://irep.iium.edu.my/45944/4/45944.pdf