S-Quinolin-2-ylmethyldithiocarbazate
In the title compound, C11H11N2S2, there is an intramolecular N—H...N [2.778(2) Angstrom] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7(1)deg with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)deg] and N—C—...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2007
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| Online Access: | http://irep.iium.edu.my/44882/ http://irep.iium.edu.my/44882/1/SQ2MDTC_%5BActa_Cryst._E63%2C_o3137-o3138%5D.pdf |
| _version_ | 1848782684901343232 |
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| author | How, Fiona Ni Foong Watkins, David J. Crouse, Karen Anne Tahir, Mohamed Ibrahim Mohamed |
| author_facet | How, Fiona Ni Foong Watkins, David J. Crouse, Karen Anne Tahir, Mohamed Ibrahim Mohamed |
| author_sort | How, Fiona Ni Foong |
| building | IIUM Repository |
| collection | Online Access |
| description | In the title compound, C11H11N2S2, there is an intramolecular N—H...N [2.778(2) Angstrom] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7(1)deg with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)deg] and N—C—S [119.05 (11)deg] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis S-methyldithiocarbazate and trans–cis S-benzyldithiocarbazate. This is due to the N—H..N hydrogen bond that exists only in the cis–trans conformation found for the title compound. |
| first_indexed | 2025-11-14T16:09:23Z |
| format | Article |
| id | iium-44882 |
| institution | International Islamic University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T16:09:23Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | iium-448822016-07-18T06:28:36Z http://irep.iium.edu.my/44882/ S-Quinolin-2-ylmethyldithiocarbazate How, Fiona Ni Foong Watkins, David J. Crouse, Karen Anne Tahir, Mohamed Ibrahim Mohamed QD Chemistry In the title compound, C11H11N2S2, there is an intramolecular N—H...N [2.778(2) Angstrom] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7(1)deg with the dithiocarbazate group. Bond angles for both S—C—S [115.66 (8)deg] and N—C—S [119.05 (11)deg] are comparable with cis–trans S-methyldithiocarbazate but differ from those found in trans–cis S-methyldithiocarbazate and trans–cis S-benzyldithiocarbazate. This is due to the N—H..N hydrogen bond that exists only in the cis–trans conformation found for the title compound. International Union of Crystallography 2007-05-18 Article PeerReviewed application/pdf en http://irep.iium.edu.my/44882/1/SQ2MDTC_%5BActa_Cryst._E63%2C_o3137-o3138%5D.pdf How, Fiona Ni Foong and Watkins, David J. and Crouse, Karen Anne and Tahir, Mohamed Ibrahim Mohamed (2007) S-Quinolin-2-ylmethyldithiocarbazate. Acta Crystallographica Section E Structure Reports Online, E63. o3137-o3138. ISSN 1600-5368 E-ISSN 2056-9890 http://journals.iucr.org/e/ doi: 10.1107/S1600536807024609 |
| spellingShingle | QD Chemistry How, Fiona Ni Foong Watkins, David J. Crouse, Karen Anne Tahir, Mohamed Ibrahim Mohamed S-Quinolin-2-ylmethyldithiocarbazate |
| title | S-Quinolin-2-ylmethyldithiocarbazate |
| title_full | S-Quinolin-2-ylmethyldithiocarbazate |
| title_fullStr | S-Quinolin-2-ylmethyldithiocarbazate |
| title_full_unstemmed | S-Quinolin-2-ylmethyldithiocarbazate |
| title_short | S-Quinolin-2-ylmethyldithiocarbazate |
| title_sort | s-quinolin-2-ylmethyldithiocarbazate |
| topic | QD Chemistry |
| url | http://irep.iium.edu.my/44882/ http://irep.iium.edu.my/44882/ http://irep.iium.edu.my/44882/ http://irep.iium.edu.my/44882/1/SQ2MDTC_%5BActa_Cryst._E63%2C_o3137-o3138%5D.pdf |