Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials

A plasticized polymer electrolyte system composed of PVDF-HFP, potassium iodide (KI), and equal weight of ethylene carbonate (EC) and propylene carbonate (PC) has been used in a dye-sensitized solar cell (DSSC). The electrolyte with the composition 40wt. %PVDF-HFP-10wt.%KI-50wt.%(EC + PC) exhibits...

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Main Authors: Mohd Noor, Mazni, Buraidah, M.H., Yusuf, S. N. F., Careem, M. A., Majid, S. R., Arof, A.K.
Format: Article
Language:English
Published: Hindawi Publishing Corporation 2011
Subjects:
Online Access:http://irep.iium.edu.my/40125/
http://irep.iium.edu.my/40125/1/Performance_of_Dye-sensitized_Solar_cells.pdf
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author Mohd Noor, Mazni
Buraidah, M.H.
Yusuf, S. N. F.
Careem, M. A.
Majid, S. R.
Arof, A.K.
author_facet Mohd Noor, Mazni
Buraidah, M.H.
Yusuf, S. N. F.
Careem, M. A.
Majid, S. R.
Arof, A.K.
author_sort Mohd Noor, Mazni
building IIUM Repository
collection Online Access
description A plasticized polymer electrolyte system composed of PVDF-HFP, potassium iodide (KI), and equal weight of ethylene carbonate (EC) and propylene carbonate (PC) has been used in a dye-sensitized solar cell (DSSC). The electrolyte with the composition 40wt. %PVDF-HFP-10wt.%KI-50wt.%(EC + PC) exhibits the highest room temperature ionic conductivity of 1.10 × 10−3 S cm−1. A small amount of iodine crystal of about 10wt.%of KI was added to the electrolyte in the liquid state to provide the redox couple for DSSC operation. The polymer electrolyte films were prepared by the solvent casting method. The DSSCs were fabricated with the electrolyte film sandwiched between a TiO2/dye photoelectrode and a Pt-counter electrode and characterized under 100mWcm−2 white light. The DSSC performance with different dyes such as Ruthenizer 535 (N3), anthocyanin, chlorophyll, and a mixture of anthocyanin and chlorophyll (v/v = 1) has been compared. The DSSC with Ruthenizer 535 (N3) dye exhibits the best performance with a short-circuit current density of 8.16mAcm−2, open-circuit voltage of 0.76 V, fill factor of 0.35, and photoconversion efficiency of 2.2%.
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institution International Islamic University Malaysia
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language English
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publishDate 2011
publisher Hindawi Publishing Corporation
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spelling iium-401252015-06-30T02:43:21Z http://irep.iium.edu.my/40125/ Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials Mohd Noor, Mazni Buraidah, M.H. Yusuf, S. N. F. Careem, M. A. Majid, S. R. Arof, A.K. QC Physics A plasticized polymer electrolyte system composed of PVDF-HFP, potassium iodide (KI), and equal weight of ethylene carbonate (EC) and propylene carbonate (PC) has been used in a dye-sensitized solar cell (DSSC). The electrolyte with the composition 40wt. %PVDF-HFP-10wt.%KI-50wt.%(EC + PC) exhibits the highest room temperature ionic conductivity of 1.10 × 10−3 S cm−1. A small amount of iodine crystal of about 10wt.%of KI was added to the electrolyte in the liquid state to provide the redox couple for DSSC operation. The polymer electrolyte films were prepared by the solvent casting method. The DSSCs were fabricated with the electrolyte film sandwiched between a TiO2/dye photoelectrode and a Pt-counter electrode and characterized under 100mWcm−2 white light. The DSSC performance with different dyes such as Ruthenizer 535 (N3), anthocyanin, chlorophyll, and a mixture of anthocyanin and chlorophyll (v/v = 1) has been compared. The DSSC with Ruthenizer 535 (N3) dye exhibits the best performance with a short-circuit current density of 8.16mAcm−2, open-circuit voltage of 0.76 V, fill factor of 0.35, and photoconversion efficiency of 2.2%. Hindawi Publishing Corporation 2011 Article PeerReviewed application/pdf en http://irep.iium.edu.my/40125/1/Performance_of_Dye-sensitized_Solar_cells.pdf Mohd Noor, Mazni and Buraidah, M.H. and Yusuf, S. N. F. and Careem, M. A. and Majid, S. R. and Arof, A.K. (2011) Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials. International Journal of Photoenergy, 2011. pp. 1-6. ISSN 1687-529X http://www.hindawi.com/journals/ijp/2011/960487/
spellingShingle QC Physics
Mohd Noor, Mazni
Buraidah, M.H.
Yusuf, S. N. F.
Careem, M. A.
Majid, S. R.
Arof, A.K.
Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials
title Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials
title_full Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials
title_fullStr Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials
title_full_unstemmed Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials
title_short Performance of dye-sensitized solar cells with (PVDF-HFP)-KI-EC-PC electrolyte and different dye materials
title_sort performance of dye-sensitized solar cells with (pvdf-hfp)-ki-ec-pc electrolyte and different dye materials
topic QC Physics
url http://irep.iium.edu.my/40125/
http://irep.iium.edu.my/40125/
http://irep.iium.edu.my/40125/1/Performance_of_Dye-sensitized_Solar_cells.pdf