Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate

Multiwall carbon nanotubes were synthesised using fixed catalyst in a chemical vapor deposition reactor. The reactor system was locally built and used to grow carbon nanotubes (CNTs) on oil palm shell powdered activated carbon (PAC). The PAC was impregnated with Fe3+ catalyst through sonication proc...

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Main Authors: Al Mamun, Abdullah, AlSaadi, Mohammed A., Alam, Md Zahangir, Sopyan, Iis
Format: Article
Language:English
English
English
Published: Springer Nature 2018
Subjects:
Online Access:http://irep.iium.edu.my/36965/
http://irep.iium.edu.my/36965/15/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm.pdf
http://irep.iium.edu.my/36965/2/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm_SCOPUS.pdf
http://irep.iium.edu.my/36965/3/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm_WOS.pdf
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author Al Mamun, Abdullah
AlSaadi, Mohammed A.
Alam, Md Zahangir
Sopyan, Iis
author_facet Al Mamun, Abdullah
AlSaadi, Mohammed A.
Alam, Md Zahangir
Sopyan, Iis
author_sort Al Mamun, Abdullah
building IIUM Repository
collection Online Access
description Multiwall carbon nanotubes were synthesised using fixed catalyst in a chemical vapor deposition reactor. The reactor system was locally built and used to grow carbon nanotubes (CNTs) on oil palm shell powdered activated carbon (PAC). The PAC was impregnated with Fe3+ catalyst through sonication process. The nano-micro composite produced in this study was named as “CNT-PAC”. Acetylene (C2H2) gas was used as carbon source compared to the use of toxic hydrocarbons such as benzene (C6H6). Synthesis parameters such as gas flow rates, temperature and reaction time were varied for high yield of the CNTs on powdered activated carbon. The CNT-PAC samples were characterized using field emission electron microscope and transmission electron microscope to confirm the growth of CNT as well as to study the morphology of the nano product. Selected well-grown CNT-PAC were further characterized using Fourier transform infrared spectroscopy, thermal gravimetric analysis and BET surface area measurement. The results showed that BET surface area was improved from 101.1 to 974.9 m2/g. The Zeta potential was − 46.1 mV. The zeta potential of the nano-micro composite indicated that the material will be in good dispersion in aqueous solution. The CNT-PAC product was also oxidized using KMnO4 to functionalise various radicals on the surfaces. The product could be potential as an adsorbent for gaseous and aqueous pollutants due to its high surface area and the presence of various functional groups.
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spelling iium-369652020-07-22T03:44:58Z http://irep.iium.edu.my/36965/ Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate Al Mamun, Abdullah AlSaadi, Mohammed A. Alam, Md Zahangir Sopyan, Iis TP248.13 Biotechnology TP670 Oils, fats, waxes Multiwall carbon nanotubes were synthesised using fixed catalyst in a chemical vapor deposition reactor. The reactor system was locally built and used to grow carbon nanotubes (CNTs) on oil palm shell powdered activated carbon (PAC). The PAC was impregnated with Fe3+ catalyst through sonication process. The nano-micro composite produced in this study was named as “CNT-PAC”. Acetylene (C2H2) gas was used as carbon source compared to the use of toxic hydrocarbons such as benzene (C6H6). Synthesis parameters such as gas flow rates, temperature and reaction time were varied for high yield of the CNTs on powdered activated carbon. The CNT-PAC samples were characterized using field emission electron microscope and transmission electron microscope to confirm the growth of CNT as well as to study the morphology of the nano product. Selected well-grown CNT-PAC were further characterized using Fourier transform infrared spectroscopy, thermal gravimetric analysis and BET surface area measurement. The results showed that BET surface area was improved from 101.1 to 974.9 m2/g. The Zeta potential was − 46.1 mV. The zeta potential of the nano-micro composite indicated that the material will be in good dispersion in aqueous solution. The CNT-PAC product was also oxidized using KMnO4 to functionalise various radicals on the surfaces. The product could be potential as an adsorbent for gaseous and aqueous pollutants due to its high surface area and the presence of various functional groups. Springer Nature 2018-10 Article PeerReviewed application/pdf en http://irep.iium.edu.my/36965/15/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm.pdf application/pdf en http://irep.iium.edu.my/36965/2/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm_SCOPUS.pdf application/pdf en http://irep.iium.edu.my/36965/3/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm_WOS.pdf Al Mamun, Abdullah and AlSaadi, Mohammed A. and Alam, Md Zahangir and Sopyan, Iis (2018) Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate. Applied Nanoscience (Switzerland), 8 (7). pp. 1767-1779. ISSN 2190-5509 E-ISSN 2190-5517 https://link.springer.com/article/10.1007/s13204-018-0861-2 10.1007/s13204-018-0861-2
spellingShingle TP248.13 Biotechnology
TP670 Oils, fats, waxes
Al Mamun, Abdullah
AlSaadi, Mohammed A.
Alam, Md Zahangir
Sopyan, Iis
Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate
title Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate
title_full Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate
title_fullStr Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate
title_full_unstemmed Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate
title_short Carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate
title_sort carbon nanotubes grown on oil palm shell powdered activated carbon as less hazardous and cheap substrate
topic TP248.13 Biotechnology
TP670 Oils, fats, waxes
url http://irep.iium.edu.my/36965/
http://irep.iium.edu.my/36965/
http://irep.iium.edu.my/36965/
http://irep.iium.edu.my/36965/15/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm.pdf
http://irep.iium.edu.my/36965/2/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm_SCOPUS.pdf
http://irep.iium.edu.my/36965/3/36935_Carbon%20nanotubes%20grown%20on%20oil%20palm_WOS.pdf