Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran

The photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran results in isomerization of the olefin. When the concentration of molybdenum hexacarbonyl is greater than 0.05M less than 1 mole of the isomerized olefin is producedfor each mole of molybdenum hexacarbonyl. The efficiency of t...

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Main Authors: Card, Roger J., Omar, Muhammad Nor
Format: Article
Language:English
Published: Penerbit UKM 1977
Subjects:
Online Access:http://irep.iium.edu.my/30235/
http://irep.iium.edu.my/30235/1/DR_NO_Sains_Malaysiana_1977.pdf
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author Card, Roger J.
Omar, Muhammad Nor
author_facet Card, Roger J.
Omar, Muhammad Nor
author_sort Card, Roger J.
building IIUM Repository
collection Online Access
description The photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran results in isomerization of the olefin. When the concentration of molybdenum hexacarbonyl is greater than 0.05M less than 1 mole of the isomerized olefin is producedfor each mole of molybdenum hexacarbonyl. The efficiency of the isomerization decreases as the concentration of molybdenum hexacarbonyl is increased. Under the condition used, the isomerization was initially rapid, but stopped completely after approximately 10 minutes.
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format Article
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institution International Islamic University Malaysia
institution_category Local University
language English
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publishDate 1977
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spelling iium-302352019-09-05T02:16:01Z http://irep.iium.edu.my/30235/ Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran Card, Roger J. Omar, Muhammad Nor QD Chemistry The photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran results in isomerization of the olefin. When the concentration of molybdenum hexacarbonyl is greater than 0.05M less than 1 mole of the isomerized olefin is producedfor each mole of molybdenum hexacarbonyl. The efficiency of the isomerization decreases as the concentration of molybdenum hexacarbonyl is increased. Under the condition used, the isomerization was initially rapid, but stopped completely after approximately 10 minutes. Penerbit UKM 1977 Article PeerReviewed application/pdf en http://irep.iium.edu.my/30235/1/DR_NO_Sains_Malaysiana_1977.pdf Card, Roger J. and Omar, Muhammad Nor (1977) Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran. Sains Malaysiana, 6 (2). pp. 133-138. ISSN 0126-6039
spellingShingle QD Chemistry
Card, Roger J.
Omar, Muhammad Nor
Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran
title Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran
title_full Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran
title_fullStr Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran
title_full_unstemmed Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran
title_short Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran
title_sort photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran
topic QD Chemistry
url http://irep.iium.edu.my/30235/
http://irep.iium.edu.my/30235/1/DR_NO_Sains_Malaysiana_1977.pdf