Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2

Separation of triglycerides in terms of fatty acid constituents in palm kernel oil (PKO) from dehulled ground palm kernel using supercritical carbon dioxide (SC-CO2) as a solvent at 40 and 80 ◦C and pressures of 20.7, 27.6, 34.5, 41.4 and 48.3MPa was studied. The extraction was continuous and PKO...

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Main Authors: Sarker, Md. Zaidul Islam, Nik Ab Rahman, Nik Norulaini, Abd Kadir, Mohd Omar
Format: Article
Language:English
Published: Elsevier Inc. 2006
Subjects:
Online Access:http://irep.iium.edu.my/24860/
http://irep.iium.edu.my/24860/1/JSFA2_Zahid.pdf
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author Sarker, Md. Zaidul Islam
Nik Ab Rahman, Nik Norulaini
Abd Kadir, Mohd Omar
author_facet Sarker, Md. Zaidul Islam
Nik Ab Rahman, Nik Norulaini
Abd Kadir, Mohd Omar
author_sort Sarker, Md. Zaidul Islam
building IIUM Repository
collection Online Access
description Separation of triglycerides in terms of fatty acid constituents in palm kernel oil (PKO) from dehulled ground palm kernel using supercritical carbon dioxide (SC-CO2) as a solvent at 40 and 80 ◦C and pressures of 20.7, 27.6, 34.5, 41.4 and 48.3MPa was studied. The extraction was continuous and PKO was fractionated into four fractions. Triglycerides with differing fatty acid contents of caprylic (C8), capric (C10), lauric (C12), myristic (C14), palmitic (C16), stearic (C18:0), oleic (C18:1) and linoleic (C18:2) acid were separated in different percentages in different fractions. About 70% of PKO comprises triglycerides with C8–C12 fatty acids and these fatty acids were mostly extracted in fractions 1and 2. As a result, higher yields were observed in these fractions, especially at pressures higher than 27.6MPa. The C16 and C18:2 components were extracted in fractions 3 and 4. These triglycerides form only a part of the remaining 30% of the fatty acid composition of PKO, hence the evidently diminishing yield in the later fractions. However, the compositions were found to be statistically significant for higher pressures and fraction times according to the type of fatty acid constituents.
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spelling iium-248602013-01-20T23:43:30Z http://irep.iium.edu.my/24860/ Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2 Sarker, Md. Zaidul Islam Nik Ab Rahman, Nik Norulaini Abd Kadir, Mohd Omar QD Chemistry Separation of triglycerides in terms of fatty acid constituents in palm kernel oil (PKO) from dehulled ground palm kernel using supercritical carbon dioxide (SC-CO2) as a solvent at 40 and 80 ◦C and pressures of 20.7, 27.6, 34.5, 41.4 and 48.3MPa was studied. The extraction was continuous and PKO was fractionated into four fractions. Triglycerides with differing fatty acid contents of caprylic (C8), capric (C10), lauric (C12), myristic (C14), palmitic (C16), stearic (C18:0), oleic (C18:1) and linoleic (C18:2) acid were separated in different percentages in different fractions. About 70% of PKO comprises triglycerides with C8–C12 fatty acids and these fatty acids were mostly extracted in fractions 1and 2. As a result, higher yields were observed in these fractions, especially at pressures higher than 27.6MPa. The C16 and C18:2 components were extracted in fractions 3 and 4. These triglycerides form only a part of the remaining 30% of the fatty acid composition of PKO, hence the evidently diminishing yield in the later fractions. However, the compositions were found to be statistically significant for higher pressures and fraction times according to the type of fatty acid constituents. Elsevier Inc. 2006 Article PeerReviewed application/pdf en cc_by_nd http://irep.iium.edu.my/24860/1/JSFA2_Zahid.pdf Sarker, Md. Zaidul Islam and Nik Ab Rahman, Nik Norulaini and Abd Kadir, Mohd Omar (2006) Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2. Journal of the Science of Food and Agriculture, 86 (7). pp. 1138-1145. ISSN 0022-5142 http://dx.doi.org/10.1002/jsfa.2479 doi:10.1002/jsfa.2479
spellingShingle QD Chemistry
Sarker, Md. Zaidul Islam
Nik Ab Rahman, Nik Norulaini
Abd Kadir, Mohd Omar
Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2
title Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2
title_full Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2
title_fullStr Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2
title_full_unstemmed Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2
title_short Separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical CO2
title_sort separation/fractionation of triglycerides in terms of fatty acid constituents in palm kernel oil using supercritical co2
topic QD Chemistry
url http://irep.iium.edu.my/24860/
http://irep.iium.edu.my/24860/
http://irep.iium.edu.my/24860/
http://irep.iium.edu.my/24860/1/JSFA2_Zahid.pdf