Possible origin of electronic effects in Rh(I)-catalyzed enantioselective hydrogenation

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Possible origin of electronic effects in Rh(I)-catalyzed enantioselective hydrogenation

Reducing the electron density of ligands switches the regioselectivity of Rh(I)-catalyzed hydrometalation. A reversal of the sense of chiral induction was also observed when chiral ligands are electronically tuned in the same manner. The combined data provide an alternative rationale for the electro...

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Bibliographic Details
Main Authors:	Wu, Hai-Chen, Abd Hamid, Shafida, Yu, Jin-Quan, Spencer, Jonathan B
Format:	Article
Language:	English
Published:	American Chemical Society 2009
Subjects:	QD Chemistry
Online Access:	http://irep.iium.edu.my/10332/ http://irep.iium.edu.my/10332/1/sw-2.pdf

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