New Structural Motifs Resulting from Internal Constraints in Chelating Bis(NHC) Ligands: A Dinuclear Ruthenium(II) Complex Featuring an η2-Arene Binding Mode and a Remarkable New Tetrameric Silver(I) Halide Form

QR Code

New Structural Motifs Resulting from Internal Constraints in Chelating Bis(NHC) Ligands: A Dinuclear Ruthenium(II) Complex Featuring an η2-Arene Binding Mode and a Remarkable New Tetrameric Silver(I) Halide Form

© 2015 American Chemical Society. A novel dinuclear ruthenium(II) complex containing two ortho-xylylene-linked bis(NHC) ligands (NHC = N-heterocyclic carbene) has been synthesized via transmetalation from a silver-NHC complex. Each ruthenium atom in the dinuclear complex is chelated through the two...

Full description

Bibliographic Details
Main Authors:	Simpson, Peter, Brown, D., Skelton, B., White, A., Baker, M.
Format:	Journal Article
Published:	American Chemical Society 2015
Online Access:	http://hdl.handle.net/20.500.11937/9965

Similar Items

A new binding geometry for an ortho-xylylene-linked bis(NHC)cyclophane: a ruthenium(II) complex with a chelating (g1-NHC)2:g6-arene ligand
by: Baker, M., et al.
Published: (2010)

Arene ruthenium chemistry
by: Bates, Richard Simon
Published: (1990)

Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II)
by: Henderson, William, et al.
Published: (2018)

Structure of the N-terminal oligomerization domain of DnaD reveals a unique tetramerization motif and provides insights into scaffold formation
by: Schneider, S., et al.
Published: (2008)

Synthesis, isolation and characterization of thiolate-bridged dinuclear complexes from [(η5-c5h5)m(co)3]2 [m=cr,mo] / Ngue Chin May
by: Ngue, Chin May
Published: (2012)

Synthesis, photophysical and electrochemical investigation of dinuclear tetrazolato-bridged rhenium complexes
by: Wright, Phillip, et al.
Published: (2012)

Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion
by: Baker, M., et al.
Published: (2007)

Copper(i) complexes: intramolecular and intermolecular arene-c– h···π(quasi-chelate ring) interactions
by: Yeo, Chien Ing *, et al.
Published: (2017)

The study of the reaction of morpholine with aryl halide and aliphatic halide
by: Dorairaaj, A/L Sivasubramaniam
Published: (2013)

Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues
by: Vaughan, Jeffrey, et al.
Published: (2015)

Solid-state and solution studies of bis-carboxylate binding by bis-amidinium calix[4]arenes
by: Camiolo, S., et al.
Published: (2001)

A new and remarkable aquatic species of Schismatoglottis (Araceae) from the Philippines
by: Boyce, P.C, et al.
Published: (2015)

Cladocera of Malaysia and Singapore with new records, redescriptions, and remarks on some species
by: Idris, B. A. G., et al.
Published: (1981)

An inverted-sandwich diuranium μ-η5:η5-cyclo-P5 complex supported by U-P5 δ-bonding
by: Gardner, Benedict M., et al.
Published: (2015)

New potential materials in advancement of photovoltaic and optoelectronic applications: metal halide perovskite nanorods
by: Choon, S.l., et al.
Published: (2023)

Synthesis and Characterization of New Chelating Resins Containing Thiourea as the Functional Group
by: Mohd Amin, Mohd Shaberi
Published: (2002)

Influence of the para-Substituent in Lanthanoid Complexes of Bis-Tetrazole-Substituted Calix[4]arenes
by: Phe, Rene, et al.
Published: (2019)

Male Tetrameres Fissispins diesing, 1861 from the domestic indigenous fowl (Gallus donesticus L.)
by: Lee, C. C., et al.
Published: (1986)

The remarkable propensity for the formation of C–H⋯π(chelate ring) interactions in the crystals of the first-row transition metal dithiocarbamates and the supramolecular architectures they sustain.
by: Tiekink, Edward R. T. *
Published: (2020)

An iridium N-heterocyclic carbene complex [IrCl(CO)2(NHC)] as a carbon monoxide-releasing molecule (CORM)
by: Simpson, Peter, et al.
Published: (2015)

Concluding remarks
by: Mohd Razman, Mohd Azraai, et al.
Published: (2020)

Concluding Remarks
by: Moosa, I., et al.
Published: (2015)

Concluding remarks
by: Rabiu Muazu, Musa, et al.
Published: (2019)

Crystalline bis(η5-cyclopentadienyl)bis(benzoato/carboxylato)titanium(IV) precursordirected route to functional titanium dioxide nanomaterials
by: Basu Baul, Tushar S., et al.
Published: (2018)

New polymer bearing hydroxamic acid chelating resin for binding of heavy metal ions
by: Lutfor, M.R., et al.
Published: (2001)

Cluster Control in Oligouranyl Complexes of p-t-Butylcalix[8]arene
by: Harrowfield, J., et al.
Published: (2010)

Enhanced deep-blue emission from Pt(II) complexes bound to 2-pyridyltetrazolate and an ortho-xylene-linked bis(NHC)cyclophane
by: McGee, Karen, et al.
Published: (2013)

Dinuclear Silver(I)-N- Heterocyclic Carbene Complexes Based On Imidazolium Derivatives: Synthesis And Biological Activities
by: Selvarajoo,, Puvana Devi
Published: (2018)

Metal ions binding by chelating ligands from new polymer bearing amidoxime functional groups
by: Lutfor, M.R., et al.
Published: (2000)

Mono- and di-anionic coordination modes of arylazosalicylates in their bis(η5-cyclopentadienyl)titanium(IV) complexes: Syntheses and crystal structures
by: Basu Baul, Tushar S., et al.
Published: (2019)

Plasma membrane dynamics and tetrameric organisation of ABCG2 transporters in mammalian cells revealed by single particle imaging techniques
by: Wong, Kelvin, et al.
Published: (2016)

A new μ-patterning method for Carbon Nanotube (CNT) forest and its remarkable optical transformation
by: Saleh, Tanveer
Published: (2013)

Synthesis, characterization, and reactivity studies of η 5 -cyclopentadienyliron dicarbonyl 4- (dimethylamino)phenyldiphenylphosphine iodide and di(µ2-chloro)(η 5 -cyclopentadienyl)4- (dimethylamino)phenyldiphenylphosphine iron-palladium iodide
by: Tong, Yong Yao
Published: (2023)

Synthesis, Structure And In Vitro Anticancer Studies Of Dinuclear Silver(I)-N-Heterocyclic Carbene Complexes Derived From Xylyl Linked Bis-Benzimidazolium Salts
by: Iqbal, Muhammad Adnan
Published: (2014)

Synthesis, Structural Characterization And Anticancer Studies Of Asymmetrical And Symmetrical Dinuclear Silver(I) Di-nheterocyclic Carbene Complexes
by: Nazri, Muhammad Zulhelmi
Published: (2022)

Open issue and concluding remarks
by: Forbes, David, et al.
Published: (2018)

A Remarkable Grey Horse
by: Moore, T., et al.
Published: (2014)

A remarkable new species of ranid (Anura: Ranidae) with phytotelmonous larvae from Mount Harriet, Andaman Island
by: Das, I.
Published: (1998)

Facile Decarboxylation of Propiolic Acid on a Ruthenium Center and Related Chemistry
by: Bowie, J., et al.
Published: (2012)

One-pot Selective Formylation and Claisen Rearrangement on Calix[4]arenes
by: Mocerino, Mauro, et al.
Published: (2006)