Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine
The enantioselectivity of the autocatalytic alkylation of 2-tert-butylpyrimidyl-5-carbaldehyde, initiated by chiral crystals of N-(2-thienylcarbonyl)glycine, is predicted computationally. The results are in accord with the correlation of the stereochemical outcome of the reaction and the absolute st...
| Main Authors: | , , , , , , , , , , |
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| Format: | Journal Article |
| Published: |
American Chemical Society
2012
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| Online Access: | http://pubs.acs.org/doi/abs/10.1021/cg300207d http://hdl.handle.net/20.500.11937/9789 |
| _version_ | 1848746051307044864 |
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| author | Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K. |
| author_facet | Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K. |
| author_sort | Carter, Damien |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The enantioselectivity of the autocatalytic alkylation of 2-tert-butylpyrimidyl-5-carbaldehyde, initiated by chiral crystals of N-(2-thienylcarbonyl)glycine, is predicted computationally. The results are in accord with the correlation of the stereochemical outcome of the reaction and the absolute structure of the crystals determined by the anomalous dispersion of X-rays and circular dichroism spectroscopy. |
| first_indexed | 2025-11-14T06:27:06Z |
| format | Journal Article |
| id | curtin-20.500.11937-9789 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:27:06Z |
| publishDate | 2012 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-97892019-02-19T05:35:29Z Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K. The enantioselectivity of the autocatalytic alkylation of 2-tert-butylpyrimidyl-5-carbaldehyde, initiated by chiral crystals of N-(2-thienylcarbonyl)glycine, is predicted computationally. The results are in accord with the correlation of the stereochemical outcome of the reaction and the absolute structure of the crystals determined by the anomalous dispersion of X-rays and circular dichroism spectroscopy. 2012 Journal Article http://hdl.handle.net/20.500.11937/9789 http://pubs.acs.org/doi/abs/10.1021/cg300207d American Chemical Society restricted |
| spellingShingle | Carter, Damien Rohl, Andrew Shtukenberg, A. Bian, S. Hu, C. Baylon, L. Kahr, B. Mineki, H. Abe, K. Kawasaki, T. Soai, K. Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine |
| title | Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine |
| title_full | Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine |
| title_fullStr | Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine |
| title_full_unstemmed | Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine |
| title_short | Prediction of Soai Reaction Enantioselectivity Induced by Crystals of N-(2-Thienylcarbonyl)glycine |
| title_sort | prediction of soai reaction enantioselectivity induced by crystals of n-(2-thienylcarbonyl)glycine |
| url | http://pubs.acs.org/doi/abs/10.1021/cg300207d http://hdl.handle.net/20.500.11937/9789 |