Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link
Lithium and sodium salts of the closo-carbadodecaborate anion [CB11H12]- have been shown to form stable solid-state electrolytes with excellent ionic conductivity for all-solid-state batteries (ASSB). However, potential commercial application is currently hindered by the difficult, low-yielding, and...
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| Format: | Journal Article |
| Language: | English |
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AMER CHEMICAL SOC
2021
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| Subjects: | |
| Online Access: | http://purl.org/au-research/grants/arc/FT160100303 http://hdl.handle.net/20.500.11937/97014 |
| _version_ | 1848766216875802624 |
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| author | Berger, Amanda Buckley, Craig Paskevicius, Mark |
| author_facet | Berger, Amanda Buckley, Craig Paskevicius, Mark |
| author_sort | Berger, Amanda |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Lithium and sodium salts of the closo-carbadodecaborate anion [CB11H12]- have been shown to form stable solid-state electrolytes with excellent ionic conductivity for all-solid-state batteries (ASSB). However, potential commercial application is currently hindered by the difficult, low-yielding, and expensive synthetic pathways. We report a novel and cost-effective method to synthesize the [CB11H12]- anion in a 40% yield from [B11H14]-, which can be synthesized using common laboratory reagents. The method avoids the use of expensive and dangerous reagents such as NaH, decaborane, and CF3SiMe3 and shows excellent reproducibility in product yield and purity. |
| first_indexed | 2025-11-14T11:47:38Z |
| format | Journal Article |
| id | curtin-20.500.11937-97014 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T11:47:38Z |
| publishDate | 2021 |
| publisher | AMER CHEMICAL SOC |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-970142025-02-28T05:28:57Z Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link Berger, Amanda Buckley, Craig Paskevicius, Mark Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry SOLID ELECTROLYTES CARBORANES CONDUCTION CHEMISTRY INSERTION LITHIUM ANIONS Lithium and sodium salts of the closo-carbadodecaborate anion [CB11H12]- have been shown to form stable solid-state electrolytes with excellent ionic conductivity for all-solid-state batteries (ASSB). However, potential commercial application is currently hindered by the difficult, low-yielding, and expensive synthetic pathways. We report a novel and cost-effective method to synthesize the [CB11H12]- anion in a 40% yield from [B11H14]-, which can be synthesized using common laboratory reagents. The method avoids the use of expensive and dangerous reagents such as NaH, decaborane, and CF3SiMe3 and shows excellent reproducibility in product yield and purity. 2021 Journal Article http://hdl.handle.net/20.500.11937/97014 10.1021/acs.inorgchem.1c01896 English http://purl.org/au-research/grants/arc/FT160100303 AMER CHEMICAL SOC fulltext |
| spellingShingle | Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry SOLID ELECTROLYTES CARBORANES CONDUCTION CHEMISTRY INSERTION LITHIUM ANIONS Berger, Amanda Buckley, Craig Paskevicius, Mark Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link |
| title | Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link |
| title_full | Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link |
| title_fullStr | Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link |
| title_full_unstemmed | Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link |
| title_short | Synthesis of closo-CB11H12– Salts Using Common Laboratory ReagentsClick to copy article link |
| title_sort | synthesis of closo-cb11h12– salts using common laboratory reagentsclick to copy article link |
| topic | Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry SOLID ELECTROLYTES CARBORANES CONDUCTION CHEMISTRY INSERTION LITHIUM ANIONS |
| url | http://purl.org/au-research/grants/arc/FT160100303 http://hdl.handle.net/20.500.11937/97014 |