Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review

Despite being widely used in people's daily life, the safety issue of lithium-ion batteries (LIBs) has become the major barrier for them to be applied in electrical vehicles (EVs) or large-scale energy storage. Typically, due to the use of liquid electrolytes containing flammable solvents which...

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Main Authors: Cao, Chencheng, Zhong, Yijun, Shao, Zongping
Format: Journal Article
Published: 2023
Online Access:http://purl.org/au-research/grants/arc/DP200103332
http://hdl.handle.net/20.500.11937/96654
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author Cao, Chencheng
Zhong, Yijun
Shao, Zongping
author_facet Cao, Chencheng
Zhong, Yijun
Shao, Zongping
author_sort Cao, Chencheng
building Curtin Institutional Repository
collection Online Access
description Despite being widely used in people's daily life, the safety issue of lithium-ion batteries (LIBs) has become the major barrier for them to be applied in electrical vehicles (EVs) or large-scale energy storage. Typically, due to the use of liquid electrolytes containing flammable solvents which are easily oxidized by excessive and accumulated heat, the potential thermal runaway is a major safety concern for traditional LIBs. A strategy for a safer electrolyte design is controlling the flammability and volatility of the liquid electrolytes, to effectively prevent thermal runaway, thus avoiding fire or other risks. Through this study, the mechanisms of thermal runaway and the recent progress in electrolyte engineering toward LIBs were summarized, covering the major strategies including adding flame-retardants, the utilization of ionic liquid electrolytes and solid electrolytes. The characteristics, strengths and weaknesses of different strategies were discussed. New designing directions of safer electrolytes for the LIBs were also provided.
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spelling curtin-20.500.11937-966542025-01-24T06:39:44Z Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review Cao, Chencheng Zhong, Yijun Shao, Zongping Despite being widely used in people's daily life, the safety issue of lithium-ion batteries (LIBs) has become the major barrier for them to be applied in electrical vehicles (EVs) or large-scale energy storage. Typically, due to the use of liquid electrolytes containing flammable solvents which are easily oxidized by excessive and accumulated heat, the potential thermal runaway is a major safety concern for traditional LIBs. A strategy for a safer electrolyte design is controlling the flammability and volatility of the liquid electrolytes, to effectively prevent thermal runaway, thus avoiding fire or other risks. Through this study, the mechanisms of thermal runaway and the recent progress in electrolyte engineering toward LIBs were summarized, covering the major strategies including adding flame-retardants, the utilization of ionic liquid electrolytes and solid electrolytes. The characteristics, strengths and weaknesses of different strategies were discussed. New designing directions of safer electrolytes for the LIBs were also provided. 2023 Journal Article http://hdl.handle.net/20.500.11937/96654 10.1002/cjoc.202200588 http://purl.org/au-research/grants/arc/DP200103332 http://purl.org/au-research/grants/arc/DP200103315 restricted
spellingShingle Cao, Chencheng
Zhong, Yijun
Shao, Zongping
Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review
title Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review
title_full Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review
title_fullStr Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review
title_full_unstemmed Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review
title_short Electrolyte Engineering for Safer Lithium-Ion Batteries: A Review
title_sort electrolyte engineering for safer lithium-ion batteries: a review
url http://purl.org/au-research/grants/arc/DP200103332
http://purl.org/au-research/grants/arc/DP200103332
http://hdl.handle.net/20.500.11937/96654