Elucidating the Mechanism of Efficient Eu(III) and Yb(III) Sensitisation from a Re(I) Tetrazolato Triangular Assembly

Elucidating the Mechanism of Efficient Eu(III) and Yb(III) Sensitisation from a Re(I) Tetrazolato Triangular Assembly

The reaction of Re(CO)5Br with deprotonated 1H-(5-(2,2′:6′,2′′-terpyridine)pyrid-2-yl)tetrazole yields a triangular assembly formed by tricarbonyl Re(I) vertices. Photophysical measurements reveal blue-green emission with a maximum at 520 nm, 32 % quantum yield, and 2430 ns long-lived excited state...

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Bibliographic Details
Main Authors: Wright, P.J., Pfrunder, M.C., Etchells, I.M., Haghighatbin, M.A., Raiteri, Paolo, Ogden, Mark, Stagni, S., Hogan, C.F., Cameron, L.J., Moore, E.G., Massi, Max
Format: Journal Article
Language:English
Published: 2024
Subjects:
europium
luminescence
rhenium
sensitisation
ytterbium
Online Access:http://purl.org/au-research/grants/arc/DP240103097
http://hdl.handle.net/20.500.11937/95991

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