Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale
This thesis investigates the catalysis of azide–alkyne cycloaddition at silicon–solution interfaces through the application of external electric fields. It extended experimental platforms to harness electrostatic catalysis from molecular scale to a larger electrode interfaces. It identifies isomers...
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| Format: | Thesis |
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Curtin University
2024
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| Online Access: | http://hdl.handle.net/20.500.11937/95954 |
| _version_ | 1848766063786852352 |
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| author | Li, Tiexin |
| author_facet | Li, Tiexin |
| author_sort | Li, Tiexin |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | This thesis investigates the catalysis of azide–alkyne cycloaddition at silicon–solution interfaces through the application of external electric fields. It extended experimental platforms to harness electrostatic catalysis from molecular scale to a larger electrode interfaces. It identifies isomers produced by the catalysis reaction and details the experimental conditions needed. Moreover, it introduces a novel Si–D surface strategy that protects silicon from oxidation, thereby overcoming data interpretation challenges and enhancing electrostatic catalysis in industrial settings. |
| first_indexed | 2025-11-14T11:45:12Z |
| format | Thesis |
| id | curtin-20.500.11937-95954 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T11:45:12Z |
| publishDate | 2024 |
| publisher | Curtin University |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-959542024-09-25T07:40:22Z Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale Li, Tiexin This thesis investigates the catalysis of azide–alkyne cycloaddition at silicon–solution interfaces through the application of external electric fields. It extended experimental platforms to harness electrostatic catalysis from molecular scale to a larger electrode interfaces. It identifies isomers produced by the catalysis reaction and details the experimental conditions needed. Moreover, it introduces a novel Si–D surface strategy that protects silicon from oxidation, thereby overcoming data interpretation challenges and enhancing electrostatic catalysis in industrial settings. 2024 Thesis http://hdl.handle.net/20.500.11937/95954 Curtin University restricted |
| spellingShingle | Li, Tiexin Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale |
| title | Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale |
| title_full | Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale |
| title_fullStr | Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale |
| title_full_unstemmed | Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale |
| title_short | Electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale |
| title_sort | electrostatic catalysis of azide–alkyne click reactions from the nanoscale to the macroscale |
| url | http://hdl.handle.net/20.500.11937/95954 |