Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.

The recycling of spent lithium-ion batteries (LIBs) can not only reduce the potential harm caused by solid waste piles to the local environment but also provide raw materials for manufacturing new batteries. Flotation is an alternative approach to achieve the selective separation of cathode and anod...

Full description

Bibliographic Details
Main Authors: Ren, Xibing, Bu, Xiangning, Tong, Zheng, Dong, Lisha, Ma, Zhicheng, Wang, Jincheng, Cao, Mingzheng, Qiu, Song
Format: Journal Article
Language:English
Published: 2024
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/95212
_version_ 1848765986564472832
author Ren, Xibing
Bu, Xiangning
Tong, Zheng
Dong, Lisha
Ma, Zhicheng
Wang, Jincheng
Cao, Mingzheng
Qiu, Song
author_facet Ren, Xibing
Bu, Xiangning
Tong, Zheng
Dong, Lisha
Ma, Zhicheng
Wang, Jincheng
Cao, Mingzheng
Qiu, Song
author_sort Ren, Xibing
building Curtin Institutional Repository
collection Online Access
description The recycling of spent lithium-ion batteries (LIBs) can not only reduce the potential harm caused by solid waste piles to the local environment but also provide raw materials for manufacturing new batteries. Flotation is an alternative approach to achieve the selective separation of cathode and anode active materials from spent LIBs. However, the presence of organic binder on the surface of hydrophilic lithium transition-metal oxides results in losses of cathode materials in the froth phase. In this study, plasma treatment was utilized to remove organic layers from cathode and anode active materials. Firstly, the correlations between plasma treatment parameters (e.g., input power, air flowrate, and treatment time) were explored and the contact angles of cathode and anode active materials were investigated by the response surface methodology. Secondly, differences in the flotation recoveries of cathode and anode active materials were enhanced with plasma modification prior to flotation, which is consistent with the contact angle measurement. Finally, the plasma-modification mechanisms of hydrophobicity of cathode and anode active materials were discussed according to Fourier Transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses. The proposed method could be a promising tool to enhance the flotation separation efficiency of cathode and anode active materials for the recycling of spent LIBs.
first_indexed 2025-11-14T11:43:58Z
format Journal Article
id curtin-20.500.11937-95212
institution Curtin University Malaysia
institution_category Local University
language eng
last_indexed 2025-11-14T11:43:58Z
publishDate 2024
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-952122024-07-03T03:04:14Z Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries. Ren, Xibing Bu, Xiangning Tong, Zheng Dong, Lisha Ma, Zhicheng Wang, Jincheng Cao, Mingzheng Qiu, Song Cathode and anode materials Contact angle measurement Flotation separation selectivity Plasma treatment Spent lithium-ion batteries The recycling of spent lithium-ion batteries (LIBs) can not only reduce the potential harm caused by solid waste piles to the local environment but also provide raw materials for manufacturing new batteries. Flotation is an alternative approach to achieve the selective separation of cathode and anode active materials from spent LIBs. However, the presence of organic binder on the surface of hydrophilic lithium transition-metal oxides results in losses of cathode materials in the froth phase. In this study, plasma treatment was utilized to remove organic layers from cathode and anode active materials. Firstly, the correlations between plasma treatment parameters (e.g., input power, air flowrate, and treatment time) were explored and the contact angles of cathode and anode active materials were investigated by the response surface methodology. Secondly, differences in the flotation recoveries of cathode and anode active materials were enhanced with plasma modification prior to flotation, which is consistent with the contact angle measurement. Finally, the plasma-modification mechanisms of hydrophobicity of cathode and anode active materials were discussed according to Fourier Transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses. The proposed method could be a promising tool to enhance the flotation separation efficiency of cathode and anode active materials for the recycling of spent LIBs. 2024 Journal Article http://hdl.handle.net/20.500.11937/95212 10.1016/j.wasman.2024.05.039 eng restricted
spellingShingle Cathode and anode materials
Contact angle measurement
Flotation separation selectivity
Plasma treatment
Spent lithium-ion batteries
Ren, Xibing
Bu, Xiangning
Tong, Zheng
Dong, Lisha
Ma, Zhicheng
Wang, Jincheng
Cao, Mingzheng
Qiu, Song
Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.
title Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.
title_full Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.
title_fullStr Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.
title_full_unstemmed Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.
title_short Influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.
title_sort influences of plasma treatment parameters on the hydrophobicity of cathode and anode materials from spent lithium-ion batteries.
topic Cathode and anode materials
Contact angle measurement
Flotation separation selectivity
Plasma treatment
Spent lithium-ion batteries
url http://hdl.handle.net/20.500.11937/95212