Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development

In this study, lithium slag was utilised as a supplementary cementitious material (SCM) to develop pozzolanic activity and reduce CO2 emissions related to cement production, with a focus on comprehensive chemical tests and microstructural assessments. Lithium slag was primarily characterised through...

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Main Authors: Rahman, SM Arifur, Dodd, Aaron, Khair, Sanjida, Shaikh, Faiz, Sarker, Prabir, Hosan, Anwar
Format: Journal Article
Published: Elsevier 2023
Online Access:http://purl.org/au-research/grants/arc/DP200102784
http://hdl.handle.net/20.500.11937/94756
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author Rahman, SM Arifur
Dodd, Aaron
Khair, Sanjida
Shaikh, Faiz
Sarker, Prabir
Hosan, Anwar
author_facet Rahman, SM Arifur
Dodd, Aaron
Khair, Sanjida
Shaikh, Faiz
Sarker, Prabir
Hosan, Anwar
author_sort Rahman, SM Arifur
building Curtin Institutional Repository
collection Online Access
description In this study, lithium slag was utilised as a supplementary cementitious material (SCM) to develop pozzolanic activity and reduce CO2 emissions related to cement production, with a focus on comprehensive chemical tests and microstructural assessments. Lithium slag was primarily characterised through laser particle size analyser, X-ray fluorescence, X-ray diffraction, scanning transmission electron microscopy coupled with energy dispersive X-ray spectroscopy, and thermogravimetry. These tests indicate that lithium slag holds 31.6% amorphous phase with rich aluminosilicate minerals, making it an excellent candidate as pozzolan. The unsaturated lime and electrical conductivity pozzolanic activity precursor tests evaluated the potentiality of using lithium slag as a low carbon pozzolan. The optimum percentage of lithium slag as a supplementary cementitious material was determined from Frattini, strength activity index, and R3 tests by replacing 0–60% cement. Results show that 40% lithium slag mortar could achieve 93% strength activity index in 28 days. The microstructure development of lithium slag was assessed and ettringite, monocarboaluminate, and intermixed calcium aluminosilicate hydrates were formed at 56 days.
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institution Curtin University Malaysia
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last_indexed 2025-11-14T11:42:50Z
publishDate 2023
publisher Elsevier
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spelling curtin-20.500.11937-947562024-05-07T05:52:11Z Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development Rahman, SM Arifur Dodd, Aaron Khair, Sanjida Shaikh, Faiz Sarker, Prabir Hosan, Anwar In this study, lithium slag was utilised as a supplementary cementitious material (SCM) to develop pozzolanic activity and reduce CO2 emissions related to cement production, with a focus on comprehensive chemical tests and microstructural assessments. Lithium slag was primarily characterised through laser particle size analyser, X-ray fluorescence, X-ray diffraction, scanning transmission electron microscopy coupled with energy dispersive X-ray spectroscopy, and thermogravimetry. These tests indicate that lithium slag holds 31.6% amorphous phase with rich aluminosilicate minerals, making it an excellent candidate as pozzolan. The unsaturated lime and electrical conductivity pozzolanic activity precursor tests evaluated the potentiality of using lithium slag as a low carbon pozzolan. The optimum percentage of lithium slag as a supplementary cementitious material was determined from Frattini, strength activity index, and R3 tests by replacing 0–60% cement. Results show that 40% lithium slag mortar could achieve 93% strength activity index in 28 days. The microstructure development of lithium slag was assessed and ettringite, monocarboaluminate, and intermixed calcium aluminosilicate hydrates were formed at 56 days. 2023 Journal Article http://hdl.handle.net/20.500.11937/94756 10.1016/j.cemconcomp.2023.105262 http://purl.org/au-research/grants/arc/DP200102784 https://creativecommons.org/licenses/by-nc/4.0/ Elsevier fulltext
spellingShingle Rahman, SM Arifur
Dodd, Aaron
Khair, Sanjida
Shaikh, Faiz
Sarker, Prabir
Hosan, Anwar
Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development
title Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development
title_full Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development
title_fullStr Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development
title_full_unstemmed Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development
title_short Assessment of lithium slag as a supplementary cementitious material: Pozzolanic activity and microstructure development
title_sort assessment of lithium slag as a supplementary cementitious material: pozzolanic activity and microstructure development
url http://purl.org/au-research/grants/arc/DP200102784
http://hdl.handle.net/20.500.11937/94756