Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex
The syntheses, structural characterisation, and magnetic and spectroscopic properties of three new polymorphs of the spin-crossover complex [Fe(sal2-trien)][Ni(dmit)2] are reported. The results are discussed as a function of their intra- and intermolecular arrangement. Correlation of their crystal s...
| Main Authors: | , , , , |
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| Format: | Journal Article |
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Royal Society of Chemistry
2009
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| Online Access: | http://pubs.rsc.org/en/Content/ArticleLanding/2009/NJ/b901779h#!divAbstract http://hdl.handle.net/20.500.11937/9447 |
| _version_ | 1848745952692666368 |
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| author | Faulmann, C. Szilagyi, Petra Jacob, K. Chahine, J. Valade, L. |
| author_facet | Faulmann, C. Szilagyi, Petra Jacob, K. Chahine, J. Valade, L. |
| author_sort | Faulmann, C. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The syntheses, structural characterisation, and magnetic and spectroscopic properties of three new polymorphs of the spin-crossover complex [Fe(sal2-trien)][Ni(dmit)2] are reported. The results are discussed as a function of their intra- and intermolecular arrangement. Correlation of their crystal structures and magnetic properties suggest that some torsion angles play a significant role in the magnetic properties of this class of compounds. Intermolecular contacts are also of importance, and the nature of the short contacts between molecular species seems to be more crucial than their number in the allowance of spin-crossover. |
| first_indexed | 2025-11-14T06:25:32Z |
| format | Journal Article |
| id | curtin-20.500.11937-9447 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:25:32Z |
| publishDate | 2009 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-94472018-12-14T00:47:47Z Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex Faulmann, C. Szilagyi, Petra Jacob, K. Chahine, J. Valade, L. The syntheses, structural characterisation, and magnetic and spectroscopic properties of three new polymorphs of the spin-crossover complex [Fe(sal2-trien)][Ni(dmit)2] are reported. The results are discussed as a function of their intra- and intermolecular arrangement. Correlation of their crystal structures and magnetic properties suggest that some torsion angles play a significant role in the magnetic properties of this class of compounds. Intermolecular contacts are also of importance, and the nature of the short contacts between molecular species seems to be more crucial than their number in the allowance of spin-crossover. 2009 Journal Article http://hdl.handle.net/20.500.11937/9447 http://pubs.rsc.org/en/Content/ArticleLanding/2009/NJ/b901779h#!divAbstract Royal Society of Chemistry restricted |
| spellingShingle | Faulmann, C. Szilagyi, Petra Jacob, K. Chahine, J. Valade, L. Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex |
| title | Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex |
| title_full | Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex |
| title_fullStr | Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex |
| title_full_unstemmed | Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex |
| title_short | Polymorphism and its effects on the magnetic behaviour of the [Fe(sal2-trien)][Ni(dmit)2] spin-crossover complex |
| title_sort | polymorphism and its effects on the magnetic behaviour of the [fe(sal2-trien)][ni(dmit)2] spin-crossover complex |
| url | http://pubs.rsc.org/en/Content/ArticleLanding/2009/NJ/b901779h#!divAbstract http://hdl.handle.net/20.500.11937/9447 |