Reaction Mechanisms of Acid-Catalyzed Hydrothermal Decomposition of Glucose and Fructose

This PhD study investigates the glucose and fructose hydrothermal decomposition under acid catalytic conditions, providing an in-deep understanding of reaction mechanisms, especially 5-hydroxymethylfurfural formation mechanism during sugar decomposition. Furthermore, the study indicates that the inc...

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Bibliographic Details
Main Author: Wu, Zhiliang
Format: Thesis
Published: Curtin University 2022
Online Access:http://hdl.handle.net/20.500.11937/92342
Description
Summary:This PhD study investigates the glucose and fructose hydrothermal decomposition under acid catalytic conditions, providing an in-deep understanding of reaction mechanisms, especially 5-hydroxymethylfurfural formation mechanism during sugar decomposition. Furthermore, the study indicates that the incorporation of N in acid catalysts can significantly enhance 5-HMF yield by reducing side reactions during fructose decomposition. Lastly, waste tire char (WTC) was prepared to catalyze glucose isomerization, which opens a new route to the application of WTC in biorefinery.