Perovskites for protonic ceramic fuel cells: a review

Protonic ceramic fuel cells (PCFCs), capable of harmonious and efficient conversion of chemical energy into electric power at reduced temperature enabled by fast proton conduction, are promising energy technology, which may radically re-define the whole way of energy conversion in the future, while...

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Main Authors: Cao, J., Ji, Y., Shao, Zongping
Format: Journal Article
Language:English
Published: ROYAL SOC CHEMISTRY 2022
Subjects:
Online Access:http://purl.org/au-research/grants/arc/DP200103315
http://hdl.handle.net/20.500.11937/91975
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author Cao, J.
Ji, Y.
Shao, Zongping
author_facet Cao, J.
Ji, Y.
Shao, Zongping
author_sort Cao, J.
building Curtin Institutional Repository
collection Online Access
description Protonic ceramic fuel cells (PCFCs), capable of harmonious and efficient conversion of chemical energy into electric power at reduced temperature enabled by fast proton conduction, are promising energy technology, which may radically re-define the whole way of energy conversion in the future, while their practical use is highly dependent on the availability of efficient key cell materials, i.e., electrolyte and electrodes, that should meet several important requirements, such as conductivity, stability, catalytic activity, compatibility, and cost. During the past two decades, complex oxides with the ABO3 perovskite or related structure have been extensively exploited as key materials in PCFCs, i.e., electrolyte and electrodes, due to their flexible composition with versatile properties. Rational design of perovskite and perovskite-related oxides with robust properties remains a pending research challenge, which makes in-depth understanding of the material engineering in PCFCs a specific focus of research. In this review, recent advances in the material engineering of perovskite oxides for PCFCs are summarized, and regulation strategies are presented, and applications as the electrodes and electrolyte are discussed. Importance is paid to exploiting the general rule of compositional engineering for amending the lattice structure, defect structure, and ionic transportation behavior of perovskite oxides, consequently providing useful guidance on the development of alternative perovskite materials for PCFCs and related fields.
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spelling curtin-20.500.11937-919752023-06-08T07:43:32Z Perovskites for protonic ceramic fuel cells: a review Cao, J. Ji, Y. Shao, Zongping Science & Technology Physical Sciences Technology Life Sciences & Biomedicine Chemistry, Multidisciplinary Energy & Fuels Engineering, Chemical Environmental Sciences Chemistry Engineering Environmental Sciences & Ecology DOPED BARIUM ZIRCONATE CO-DOPING STRATEGY COBALT-FREE CATHODE HIGH-PERFORMANCE CONDUCTING ELECTROLYTE IN-SITU ELECTROCHEMICAL PROPERTIES ELECTRICAL-PROPERTIES CRYSTAL-STRUCTURE SINTERING TEMPERATURE Protonic ceramic fuel cells (PCFCs), capable of harmonious and efficient conversion of chemical energy into electric power at reduced temperature enabled by fast proton conduction, are promising energy technology, which may radically re-define the whole way of energy conversion in the future, while their practical use is highly dependent on the availability of efficient key cell materials, i.e., electrolyte and electrodes, that should meet several important requirements, such as conductivity, stability, catalytic activity, compatibility, and cost. During the past two decades, complex oxides with the ABO3 perovskite or related structure have been extensively exploited as key materials in PCFCs, i.e., electrolyte and electrodes, due to their flexible composition with versatile properties. Rational design of perovskite and perovskite-related oxides with robust properties remains a pending research challenge, which makes in-depth understanding of the material engineering in PCFCs a specific focus of research. In this review, recent advances in the material engineering of perovskite oxides for PCFCs are summarized, and regulation strategies are presented, and applications as the electrodes and electrolyte are discussed. Importance is paid to exploiting the general rule of compositional engineering for amending the lattice structure, defect structure, and ionic transportation behavior of perovskite oxides, consequently providing useful guidance on the development of alternative perovskite materials for PCFCs and related fields. 2022 Journal Article http://hdl.handle.net/20.500.11937/91975 10.1039/d2ee00132b English http://purl.org/au-research/grants/arc/DP200103315 http://purl.org/au-research/grants/arc/DP200103332 ROYAL SOC CHEMISTRY restricted
spellingShingle Science & Technology
Physical Sciences
Technology
Life Sciences & Biomedicine
Chemistry, Multidisciplinary
Energy & Fuels
Engineering, Chemical
Environmental Sciences
Chemistry
Engineering
Environmental Sciences & Ecology
DOPED BARIUM ZIRCONATE
CO-DOPING STRATEGY
COBALT-FREE CATHODE
HIGH-PERFORMANCE
CONDUCTING ELECTROLYTE
IN-SITU
ELECTROCHEMICAL PROPERTIES
ELECTRICAL-PROPERTIES
CRYSTAL-STRUCTURE
SINTERING TEMPERATURE
Cao, J.
Ji, Y.
Shao, Zongping
Perovskites for protonic ceramic fuel cells: a review
title Perovskites for protonic ceramic fuel cells: a review
title_full Perovskites for protonic ceramic fuel cells: a review
title_fullStr Perovskites for protonic ceramic fuel cells: a review
title_full_unstemmed Perovskites for protonic ceramic fuel cells: a review
title_short Perovskites for protonic ceramic fuel cells: a review
title_sort perovskites for protonic ceramic fuel cells: a review
topic Science & Technology
Physical Sciences
Technology
Life Sciences & Biomedicine
Chemistry, Multidisciplinary
Energy & Fuels
Engineering, Chemical
Environmental Sciences
Chemistry
Engineering
Environmental Sciences & Ecology
DOPED BARIUM ZIRCONATE
CO-DOPING STRATEGY
COBALT-FREE CATHODE
HIGH-PERFORMANCE
CONDUCTING ELECTROLYTE
IN-SITU
ELECTROCHEMICAL PROPERTIES
ELECTRICAL-PROPERTIES
CRYSTAL-STRUCTURE
SINTERING TEMPERATURE
url http://purl.org/au-research/grants/arc/DP200103315
http://purl.org/au-research/grants/arc/DP200103315
http://hdl.handle.net/20.500.11937/91975