Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives
Developing highly efficient electrocatalysts for renewable energy conversion and environment purification has long been a research priority in the past 15 years. Covalent organic frameworks (COFs) have emerged as a burgeoning family of organic materials internally connected by covalent bonds and hav...
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| Format: | Journal Article |
| Language: | English |
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WILEY-V C H VERLAG GMBH
2021
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| Online Access: | https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/smtd.202100945 http://hdl.handle.net/20.500.11937/91970 |
| _version_ | 1848765608947089408 |
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| author | Tang, J. Su, Chao Shao, Zongping |
| author_facet | Tang, J. Su, Chao Shao, Zongping |
| author_sort | Tang, J. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Developing highly efficient electrocatalysts for renewable energy conversion and environment purification has long been a research priority in the past 15 years. Covalent organic frameworks (COFs) have emerged as a burgeoning family of organic materials internally connected by covalent bonds and have been explored as promising candidates in electrocatalysis. The reticular geometry of COFs can provide an excellent platform for precise incorporation of the active sites in the framework, and the fine-tuning hierarchical porous architectures can enable efficient accessibility of the active sites and mass transportation. Considerable advances are made in rational design and controllable fabrication of COF-based organic–inorganic hybrids, that containing organic frameworks and inorganic electroactive species to induce novel physicochemical properties, and take advantage of the synergistic effect for targeted electrocatalysis with the hybrid system. Branches of COF-based hybrids containing a diversity form of metals, metal compounds, as well as metal-free carbons have come to the fore as highly promising electrocatalysts. This review aims to provide a systematic and profound understanding of the design principles behind the COF-based hybrids for electrocatalysis applications. Particularly, the structure–activity relationship and the synergistic effects in the COF-based hybrid systems are discussed to shed some light on the future design of next-generation electrocatalysts. |
| first_indexed | 2025-11-14T11:37:58Z |
| format | Journal Article |
| id | curtin-20.500.11937-91970 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T11:37:58Z |
| publishDate | 2021 |
| publisher | WILEY-V C H VERLAG GMBH |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-919702023-06-08T07:20:56Z Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives Tang, J. Su, Chao Shao, Zongping Science & Technology Physical Sciences Technology Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Science & Technology - Other Topics Materials Science COF-based electrocatalysts COF-based hybrids covalent organic frameworks organic-inorganic hybrids HYDROGEN EVOLUTION REACTION INTRINSIC MICROPOROSITY PIMS UNIFORM INORGANIC PARTICLES COBALT PORPHYRIN FRAMEWORK REGENERATIVE FUEL-CELL DOPED CARBON MATERIALS OXYGEN-REDUCTION SOLVOTHERMAL SYNTHESIS ENERGY-CONVERSION WATER-OXIDATION COF-based electrocatalysts COF-based hybrids covalent organic frameworks organic-inorganic hybrids Developing highly efficient electrocatalysts for renewable energy conversion and environment purification has long been a research priority in the past 15 years. Covalent organic frameworks (COFs) have emerged as a burgeoning family of organic materials internally connected by covalent bonds and have been explored as promising candidates in electrocatalysis. The reticular geometry of COFs can provide an excellent platform for precise incorporation of the active sites in the framework, and the fine-tuning hierarchical porous architectures can enable efficient accessibility of the active sites and mass transportation. Considerable advances are made in rational design and controllable fabrication of COF-based organic–inorganic hybrids, that containing organic frameworks and inorganic electroactive species to induce novel physicochemical properties, and take advantage of the synergistic effect for targeted electrocatalysis with the hybrid system. Branches of COF-based hybrids containing a diversity form of metals, metal compounds, as well as metal-free carbons have come to the fore as highly promising electrocatalysts. This review aims to provide a systematic and profound understanding of the design principles behind the COF-based hybrids for electrocatalysis applications. Particularly, the structure–activity relationship and the synergistic effects in the COF-based hybrid systems are discussed to shed some light on the future design of next-generation electrocatalysts. 2021 Journal Article http://hdl.handle.net/20.500.11937/91970 10.1002/smtd.202100945 English https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/smtd.202100945 http://purl.org/au-research/grants/arc/DP200103332 http://purl.org/au-research/grants/arc/DP200103315 WILEY-V C H VERLAG GMBH unknown |
| spellingShingle | Science & Technology Physical Sciences Technology Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Science & Technology - Other Topics Materials Science COF-based electrocatalysts COF-based hybrids covalent organic frameworks organic-inorganic hybrids HYDROGEN EVOLUTION REACTION INTRINSIC MICROPOROSITY PIMS UNIFORM INORGANIC PARTICLES COBALT PORPHYRIN FRAMEWORK REGENERATIVE FUEL-CELL DOPED CARBON MATERIALS OXYGEN-REDUCTION SOLVOTHERMAL SYNTHESIS ENERGY-CONVERSION WATER-OXIDATION COF-based electrocatalysts COF-based hybrids covalent organic frameworks organic-inorganic hybrids Tang, J. Su, Chao Shao, Zongping Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives |
| title | Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives |
| title_full | Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives |
| title_fullStr | Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives |
| title_full_unstemmed | Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives |
| title_short | Covalent Organic Framework (COF)-Based Hybrids for Electrocatalysis: Recent Advances and Perspectives |
| title_sort | covalent organic framework (cof)-based hybrids for electrocatalysis: recent advances and perspectives |
| topic | Science & Technology Physical Sciences Technology Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Science & Technology - Other Topics Materials Science COF-based electrocatalysts COF-based hybrids covalent organic frameworks organic-inorganic hybrids HYDROGEN EVOLUTION REACTION INTRINSIC MICROPOROSITY PIMS UNIFORM INORGANIC PARTICLES COBALT PORPHYRIN FRAMEWORK REGENERATIVE FUEL-CELL DOPED CARBON MATERIALS OXYGEN-REDUCTION SOLVOTHERMAL SYNTHESIS ENERGY-CONVERSION WATER-OXIDATION COF-based electrocatalysts COF-based hybrids covalent organic frameworks organic-inorganic hybrids |
| url | https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/smtd.202100945 https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/smtd.202100945 https://onlinelibrary.wiley.com/doi/am-pdf/10.1002/smtd.202100945 http://hdl.handle.net/20.500.11937/91970 |