Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces

Electrochemical ion-transfer across miniaturised interfaces between immiscible electrolyte solutions (ITIES) is characterised by diffusion mass-transport limited currents. However, in the case of ion-transfer across nano-scale ITIES formed about porous silicon nitride (SiN) thin-films, it has been o...

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Main Author: Austen, Benjamin J. J.
Format: Thesis
Published: Curtin University 2022
Online Access:http://hdl.handle.net/20.500.11937/91822
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author Austen, Benjamin J. J.
author_facet Austen, Benjamin J. J.
author_sort Austen, Benjamin J. J.
building Curtin Institutional Repository
collection Online Access
description Electrochemical ion-transfer across miniaturised interfaces between immiscible electrolyte solutions (ITIES) is characterised by diffusion mass-transport limited currents. However, in the case of ion-transfer across nano-scale ITIES formed about porous silicon nitride (SiN) thin-films, it has been observed that the current usually exhibits a potential dependence. A review of existing work, physical and electrochemical characterisation, and theoretical discussion presented in this work provides new perspective on an enduring limitation of the promising SiN platform.
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format Thesis
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T11:37:44Z
publishDate 2022
publisher Curtin University
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spelling curtin-20.500.11937-918222025-05-13T02:57:42Z Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces Austen, Benjamin J. J. Electrochemical ion-transfer across miniaturised interfaces between immiscible electrolyte solutions (ITIES) is characterised by diffusion mass-transport limited currents. However, in the case of ion-transfer across nano-scale ITIES formed about porous silicon nitride (SiN) thin-films, it has been observed that the current usually exhibits a potential dependence. A review of existing work, physical and electrochemical characterisation, and theoretical discussion presented in this work provides new perspective on an enduring limitation of the promising SiN platform. 2022 Thesis http://hdl.handle.net/20.500.11937/91822 Curtin University fulltext
spellingShingle Austen, Benjamin J. J.
Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces
title Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces
title_full Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces
title_fullStr Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces
title_full_unstemmed Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces
title_short Electrochemical Characterisation of Nano-Membrane Supported Liquid-Liquid Interfaces
title_sort electrochemical characterisation of nano-membrane supported liquid-liquid interfaces
url http://hdl.handle.net/20.500.11937/91822