Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction

The emission of nitric oxide from the combustion process of fossil fuels causes air pollution problems. In addition to traditional removal methods, nitric oxide can be removed by the electrochemical reduction method. In this study, Ba0.5Sr0.5Co0.8Fe0.2O3−δ powders were synthesized using a solid-stat...

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Main Authors: Shi, Huangang, Chu, G., Tan, W., Su, Chao
Format: Journal Article
Language:English
Published: FRONTIERS MEDIA SA 2020
Subjects:
Online Access:http://purl.org/au-research/grants/arc/DE180100773
http://hdl.handle.net/20.500.11937/90769
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author Shi, Huangang
Chu, G.
Tan, W.
Su, Chao
author_facet Shi, Huangang
Chu, G.
Tan, W.
Su, Chao
author_sort Shi, Huangang
building Curtin Institutional Repository
collection Online Access
description The emission of nitric oxide from the combustion process of fossil fuels causes air pollution problems. In addition to traditional removal methods, nitric oxide can be removed by the electrochemical reduction method. In this study, Ba0.5Sr0.5Co0.8Fe0.2O3−δ powders were synthesized using a solid-state reaction method. Symmetrical cells, with Sm0.2Ce0.8O1.9 as the electrolyte and Ba0.5Sr0.5Co0.8Fe0.2O3−δ as the electrodes, were prepared as the electrochemical reactor for nitric oxide reduction. In the process of electrochemical reduction, nitric oxide reduction occurs at the cathode and oxygen evolution occurs at the anode. To study the nitric oxide reduction performance of the electrode, impedances of the symmetrical cell in different atmospheres were analyzed. For the nitric oxide conversion in symmetric cells, two different modes, dual chamber and single chamber, were applied. Results demonstrated that the denitrification performance of the double chamber was better but the single chamber mode had other advantages in its simple structure. Presliminary stability results of the single chamber symmetric cell show that the electrochemical reduction of nitric oxide in symmetric cells with BSCF performed most reliably.
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institution Curtin University Malaysia
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language English
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publishDate 2020
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spelling curtin-20.500.11937-907692023-04-12T07:45:03Z Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction Shi, Huangang Chu, G. Tan, W. Su, Chao Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry electrochemical reduction symmetric cell nitric oxide Ba0.5Sr0.5Co0.8Fe0.2O3-delta single chamber NO DECOMPOSITION TEMPERATURE PEROVSKITE REMOVAL CATHODE ZIRCONIA SCR The emission of nitric oxide from the combustion process of fossil fuels causes air pollution problems. In addition to traditional removal methods, nitric oxide can be removed by the electrochemical reduction method. In this study, Ba0.5Sr0.5Co0.8Fe0.2O3−δ powders were synthesized using a solid-state reaction method. Symmetrical cells, with Sm0.2Ce0.8O1.9 as the electrolyte and Ba0.5Sr0.5Co0.8Fe0.2O3−δ as the electrodes, were prepared as the electrochemical reactor for nitric oxide reduction. In the process of electrochemical reduction, nitric oxide reduction occurs at the cathode and oxygen evolution occurs at the anode. To study the nitric oxide reduction performance of the electrode, impedances of the symmetrical cell in different atmospheres were analyzed. For the nitric oxide conversion in symmetric cells, two different modes, dual chamber and single chamber, were applied. Results demonstrated that the denitrification performance of the double chamber was better but the single chamber mode had other advantages in its simple structure. Presliminary stability results of the single chamber symmetric cell show that the electrochemical reduction of nitric oxide in symmetric cells with BSCF performed most reliably. 2020 Journal Article http://hdl.handle.net/20.500.11937/90769 10.3389/fchem.2019.00947 English http://purl.org/au-research/grants/arc/DE180100773 http://creativecommons.org/licenses/by/4.0/ FRONTIERS MEDIA SA fulltext
spellingShingle Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
electrochemical reduction
symmetric cell
nitric oxide
Ba0.5Sr0.5Co0.8Fe0.2O3-delta
single chamber
NO
DECOMPOSITION
TEMPERATURE
PEROVSKITE
REMOVAL
CATHODE
ZIRCONIA
SCR
Shi, Huangang
Chu, G.
Tan, W.
Su, Chao
Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction
title Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction
title_full Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction
title_fullStr Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction
title_full_unstemmed Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction
title_short Electrochemical Performance of Ba0.5Sr0.5Co0.8Fe0.2O3−δ in Symmetric Cells With Sm0.2Ce0.8O1.9 Electrolyte for Nitric Oxide Reduction Reaction
title_sort electrochemical performance of ba0.5sr0.5co0.8fe0.2o3−δ in symmetric cells with sm0.2ce0.8o1.9 electrolyte for nitric oxide reduction reaction
topic Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
electrochemical reduction
symmetric cell
nitric oxide
Ba0.5Sr0.5Co0.8Fe0.2O3-delta
single chamber
NO
DECOMPOSITION
TEMPERATURE
PEROVSKITE
REMOVAL
CATHODE
ZIRCONIA
SCR
url http://purl.org/au-research/grants/arc/DE180100773
http://hdl.handle.net/20.500.11937/90769