Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia

Accessory mineral thermometry and thermodynamic modelling are fundamental tools for constraining petrogenetic models of granite magmatism. U–Pb geochronology on zircon and monazite from S-type granites emplaced within a semi-continuous, whole-crust section in the Georgetown Inlier (GTI), NE Australi...

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Main Authors: Volante, Silvia, Collins, Bill, Blereau, E., Pourteau, Amaury, Spencer, Christopher, Evans, Noreen, Barrote, Vitor, Nordsvan, A.R., Li, Zheng-Xiang, Li, J.
Format: Journal Article
Language:English
Published: SPRINGER 2020
Subjects:
Online Access:http://purl.org/au-research/grants/arc/FL150100133
http://hdl.handle.net/20.500.11937/90591
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author Volante, Silvia
Collins, Bill
Blereau, E.
Pourteau, Amaury
Spencer, Christopher
Evans, Noreen
Barrote, Vitor
Nordsvan, A.R.
Li, Zheng-Xiang
Li, J.
author_facet Volante, Silvia
Collins, Bill
Blereau, E.
Pourteau, Amaury
Spencer, Christopher
Evans, Noreen
Barrote, Vitor
Nordsvan, A.R.
Li, Zheng-Xiang
Li, J.
author_sort Volante, Silvia
building Curtin Institutional Repository
collection Online Access
description Accessory mineral thermometry and thermodynamic modelling are fundamental tools for constraining petrogenetic models of granite magmatism. U–Pb geochronology on zircon and monazite from S-type granites emplaced within a semi-continuous, whole-crust section in the Georgetown Inlier (GTI), NE Australia, indicates synchronous crystallisation at 1550 Ma. Zircon saturation temperature (Tzr) and titanium-in-zircon thermometry (T(Ti–zr)) estimate magma temperatures of ~ 795 ± 41 °C (Tzr) and ~ 845 ± 46 °C (T(Ti-zr)) in the deep crust, ~ 735 ± 30 °C (Tzr) and ~ 785 ± 30 °C (T(Ti-zr)) in the middle crust, and ~ 796 ± 45 °C (Tzr) and ~ 850 ± 40 °C (T(Ti-zr)) in the upper crust. The differing averages reflect ambient temperature conditions (Tzr) within the magma chamber, whereas the higher T(Ti-zr) values represent peak conditions of hotter melt injections. Assuming thermal equilibrium through the crust and adiabatic ascent, shallower magmas contained 4 wt% H2O, whereas deeper melts contained 7 wt% H2O. Using these H2O contents, monazite saturation temperature (Tmz) estimates agree with Tzr values. Thermodynamic modelling indicates that plagioclase, garnet and biotite were restitic phases, and that compositional variation in the GTI suites resulted from entrainment of these minerals in silicic (74–76 wt% SiO2) melts. At inferred emplacement P–T conditions of 5 kbar and 730 °C, additional H2O is required to produce sufficient melt with compositions similar to the GTI granites. Drier and hotter magmas required additional heat to raise adiabatically to upper-crustal levels. S-type granites are low-T mushes of melt and residual phases that stall and equilibrate in the middle crust, suggesting that discussions on the unreliability of zircon-based thermometers should be modulated.
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publishDate 2020
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spelling curtin-20.500.11937-905912023-03-24T04:27:04Z Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia Volante, Silvia Collins, Bill Blereau, E. Pourteau, Amaury Spencer, Christopher Evans, Noreen Barrote, Vitor Nordsvan, A.R. Li, Zheng-Xiang Li, J. Science & Technology Physical Sciences Geochemistry & Geophysics Mineralogy Zircon and monazite thermometry Water content Granitic melts Complete crustal section Phase equilibria diagrams LACHLAN FOLD BELT S-TYPE GRANITES TI-IN-ZIRCON U-PB PHASE-EQUILIBRIA WATER CONTENTS TEMPERATURE SATURATION BEARING INLIER Accessory mineral thermometry and thermodynamic modelling are fundamental tools for constraining petrogenetic models of granite magmatism. U–Pb geochronology on zircon and monazite from S-type granites emplaced within a semi-continuous, whole-crust section in the Georgetown Inlier (GTI), NE Australia, indicates synchronous crystallisation at 1550 Ma. Zircon saturation temperature (Tzr) and titanium-in-zircon thermometry (T(Ti–zr)) estimate magma temperatures of ~ 795 ± 41 °C (Tzr) and ~ 845 ± 46 °C (T(Ti-zr)) in the deep crust, ~ 735 ± 30 °C (Tzr) and ~ 785 ± 30 °C (T(Ti-zr)) in the middle crust, and ~ 796 ± 45 °C (Tzr) and ~ 850 ± 40 °C (T(Ti-zr)) in the upper crust. The differing averages reflect ambient temperature conditions (Tzr) within the magma chamber, whereas the higher T(Ti-zr) values represent peak conditions of hotter melt injections. Assuming thermal equilibrium through the crust and adiabatic ascent, shallower magmas contained 4 wt% H2O, whereas deeper melts contained 7 wt% H2O. Using these H2O contents, monazite saturation temperature (Tmz) estimates agree with Tzr values. Thermodynamic modelling indicates that plagioclase, garnet and biotite were restitic phases, and that compositional variation in the GTI suites resulted from entrainment of these minerals in silicic (74–76 wt% SiO2) melts. At inferred emplacement P–T conditions of 5 kbar and 730 °C, additional H2O is required to produce sufficient melt with compositions similar to the GTI granites. Drier and hotter magmas required additional heat to raise adiabatically to upper-crustal levels. S-type granites are low-T mushes of melt and residual phases that stall and equilibrate in the middle crust, suggesting that discussions on the unreliability of zircon-based thermometers should be modulated. 2020 Journal Article http://hdl.handle.net/20.500.11937/90591 10.1007/s00410-020-01752-7 English http://purl.org/au-research/grants/arc/FL150100133 http://creativecommons.org/licenses/by/4.0/ SPRINGER fulltext
spellingShingle Science & Technology
Physical Sciences
Geochemistry & Geophysics
Mineralogy
Zircon and monazite thermometry
Water content
Granitic melts
Complete crustal section
Phase equilibria diagrams
LACHLAN FOLD BELT
S-TYPE GRANITES
TI-IN-ZIRCON
U-PB
PHASE-EQUILIBRIA
WATER CONTENTS
TEMPERATURE
SATURATION
BEARING
INLIER
Volante, Silvia
Collins, Bill
Blereau, E.
Pourteau, Amaury
Spencer, Christopher
Evans, Noreen
Barrote, Vitor
Nordsvan, A.R.
Li, Zheng-Xiang
Li, J.
Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia
title Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia
title_full Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia
title_fullStr Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia
title_full_unstemmed Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia
title_short Reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the Georgetown igneous complex, NE Australia
title_sort reassessing zircon-monazite thermometry with thermodynamic modelling: insights from the georgetown igneous complex, ne australia
topic Science & Technology
Physical Sciences
Geochemistry & Geophysics
Mineralogy
Zircon and monazite thermometry
Water content
Granitic melts
Complete crustal section
Phase equilibria diagrams
LACHLAN FOLD BELT
S-TYPE GRANITES
TI-IN-ZIRCON
U-PB
PHASE-EQUILIBRIA
WATER CONTENTS
TEMPERATURE
SATURATION
BEARING
INLIER
url http://purl.org/au-research/grants/arc/FL150100133
http://hdl.handle.net/20.500.11937/90591