Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite

The responses of uranium-bearing accessory minerals to shock metamorphism have received growing interest, because under extreme pressure and temperature conditions, these phases can form unique microstructures and/or polymorphs and their radiometric ages can be partially to wholly reset. This study...

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Main Authors: Erickson, Timmons, Timms, Nick, Pearce, M.A., Cayron, C., Deutsch, A., Keller, L.P., Kring, D.A.
Format: Journal Article
Language:English
Published: GEOLOGICAL SOC AMER, INC 2019
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/90171
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author Erickson, Timmons
Timms, Nick
Pearce, M.A.
Cayron, C.
Deutsch, A.
Keller, L.P.
Kring, D.A.
author_facet Erickson, Timmons
Timms, Nick
Pearce, M.A.
Cayron, C.
Deutsch, A.
Keller, L.P.
Kring, D.A.
author_sort Erickson, Timmons
building Curtin Institutional Repository
collection Online Access
description The responses of uranium-bearing accessory minerals to shock metamorphism have received growing interest, because under extreme pressure and temperature conditions, these phases can form unique microstructures and/or polymorphs and their radiometric ages can be partially to wholly reset. This study presents new, high-resolution electron backscatter diffraction microstructural analyses of shock-deformed monazite, (La, Ce, Th)PO4, from the Haughton Dome, Nunavut, Canada, and the Nördlinger-Ries Crater, southern Germany. At each locality, shocked monazite grains contain distinctive lamellae comprising interlocking laths in four systematic crystallographic orientations. Modelling of orientation relationships among these lath-textured microstructures reveals that they were produced by reversion from lamellae of a previously undescribed high-pressure polymorph with a tetragonal symmetry. This is the first report of polymorphism found in natural (La, Ce, Th)PO4. The orientation relationships, lamellar forms, and ready reversion to monazite at low pressures are consistent with a deviatoric transformation. The former presence of this new (La, Ce, Th)PO4 polymorph is detected in moderately to highly shocked rocks, suggesting that it may be common at other impact craters.
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spelling curtin-20.500.11937-901712023-02-09T06:19:58Z Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite Erickson, Timmons Timms, Nick Pearce, M.A. Cayron, C. Deutsch, A. Keller, L.P. Kring, D.A. Science & Technology Physical Sciences Geology HAUGHTON IMPACT STRUCTURE COMPUTER-PROGRAM PARENT GRAINS METAMORPHISM CONSTRAINTS ZIRCON ROCKS AGE The responses of uranium-bearing accessory minerals to shock metamorphism have received growing interest, because under extreme pressure and temperature conditions, these phases can form unique microstructures and/or polymorphs and their radiometric ages can be partially to wholly reset. This study presents new, high-resolution electron backscatter diffraction microstructural analyses of shock-deformed monazite, (La, Ce, Th)PO4, from the Haughton Dome, Nunavut, Canada, and the Nördlinger-Ries Crater, southern Germany. At each locality, shocked monazite grains contain distinctive lamellae comprising interlocking laths in four systematic crystallographic orientations. Modelling of orientation relationships among these lath-textured microstructures reveals that they were produced by reversion from lamellae of a previously undescribed high-pressure polymorph with a tetragonal symmetry. This is the first report of polymorphism found in natural (La, Ce, Th)PO4. The orientation relationships, lamellar forms, and ready reversion to monazite at low pressures are consistent with a deviatoric transformation. The former presence of this new (La, Ce, Th)PO4 polymorph is detected in moderately to highly shocked rocks, suggesting that it may be common at other impact craters. 2019 Journal Article http://hdl.handle.net/20.500.11937/90171 10.1130/G46008.1 English GEOLOGICAL SOC AMER, INC restricted
spellingShingle Science & Technology
Physical Sciences
Geology
HAUGHTON IMPACT STRUCTURE
COMPUTER-PROGRAM
PARENT GRAINS
METAMORPHISM
CONSTRAINTS
ZIRCON
ROCKS
AGE
Erickson, Timmons
Timms, Nick
Pearce, M.A.
Cayron, C.
Deutsch, A.
Keller, L.P.
Kring, D.A.
Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite
title Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite
title_full Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite
title_fullStr Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite
title_full_unstemmed Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite
title_short Shock-produced high-pressure (La, Ce, Th)PO4 polymorph revealed by microstructural phase heritage of monazite
title_sort shock-produced high-pressure (la, ce, th)po4 polymorph revealed by microstructural phase heritage of monazite
topic Science & Technology
Physical Sciences
Geology
HAUGHTON IMPACT STRUCTURE
COMPUTER-PROGRAM
PARENT GRAINS
METAMORPHISM
CONSTRAINTS
ZIRCON
ROCKS
AGE
url http://hdl.handle.net/20.500.11937/90171