Monazite as a monitor for melt-rock interaction during cooling and exhumation

Granulite facies cordierite–garnet–biotite gneisses from the southeastern Reynolds Range, central Australia, contain both orthopyroxene-bearing and orthopyroxene-free quartzofeldspathic leucosomes. Mineral reaction microstructures at the interface of gneiss and leucosome observed in outcrop and petr...

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Main Authors: Prent, Alexander M., Beinlich, Andreas, Morrissey, L.J., Raimondo, T., Clark, Chris, Putnis, Andrew
Format: Journal Article
Language:English
Published: WILEY 2019
Subjects:
Online Access:https://unisa.alma.exlibrisgroup.com/view/delivery/61USOUTHAUS_INST/12174973280001831
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author Prent, Alexander M.
Beinlich, Andreas
Morrissey, L.J.
Raimondo, T.
Clark, Chris
Putnis, Andrew
author_facet Prent, Alexander M.
Beinlich, Andreas
Morrissey, L.J.
Raimondo, T.
Clark, Chris
Putnis, Andrew
author_sort Prent, Alexander M.
building Curtin Institutional Repository
collection Online Access
description Granulite facies cordierite–garnet–biotite gneisses from the southeastern Reynolds Range, central Australia, contain both orthopyroxene-bearing and orthopyroxene-free quartzofeldspathic leucosomes. Mineral reaction microstructures at the interface of gneiss and leucosome observed in outcrop and petrographically, reflect melt-rock interaction during crystallization. Accessory monazite, susceptible to fluid alteration, dissolution and recrystallization at high temperature, is tested for its applicability to constrain the chemical and P–T–time evolution of melt-rock reactions during crystallization upon cooling. Bulk rock geochemistry and phase equilibria modelling constrain peak pressure and temperature conditions to 6.5–7.5 kbar and ~850°C, and U–Pb geochronology constrains the timing of monazite crystallization to 1.55 Ga, coeval with the Chewings Orogeny. Modelling predicts the presence of up to 15 vol.% melt at peak metamorphic conditions. Upon cooling below 800°C, melt extraction and in situ crystallization of melt decrease the melt volume to less than 7%, at which time it becomes entrapped and melt pockets induce replacement reactions in the adjacent host rock. Replacement reactions of garnet, orthopyroxene and K-feldspar liberate Y, REE, Eu and U in addition to Mg, Fe, Al, Si and K. We demonstrate that distinguishing between monazite varieties solely on the basis of U–Pb ages cannot solve the chronological order of events in this study, nor does it tie monazite to the evolution of melt or stability of rock-forming minerals. Rather, we argue that analyses of various internal monazite textures, their composition and overprinting relations allow us to identify the chronology of events following the metamorphic peak. We infer that retrograde reactions involving garnet, orthopyroxene and K-feldspar can be attributed to melt-rock interaction subsequent to partial melting, which is reflected in the development of compositionally distinct monazite textural domains. Internal monazite textures and their composition are consistent with dissolution and precipitation reactions induced by a high-T melt. Monazite rims enriched in Y, HREE, Eu and U indicate an increased availability of these elements, consistent with the breakdown of orthopyroxene, garnet and K-feldspar observed petrographically. Our study indicates that compositional and textural analysis of monazite in relation to major rock-forming minerals can be used to infer the post-peak chemical evolution of partial melts during high- to ultrahigh-temperature metamorphism.
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institution Curtin University Malaysia
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spelling curtin-20.500.11937-900132023-03-15T07:26:29Z Monazite as a monitor for melt-rock interaction during cooling and exhumation Prent, Alexander M. Beinlich, Andreas Morrissey, L.J. Raimondo, T. Clark, Chris Putnis, Andrew Science & Technology Physical Sciences Geology geochronology granulite melt-rock interaction monazite trace elements GRANULITE-FACIES METAMORPHISM SOUTHEASTERN REYNOLDS RANGE CENTRAL AUSTRALIA ARUNTA REGION SHEAR ZONES FLUID-FLOW HIGH-T HYDROTHERMAL ALTERATION PB GEOCHRONOLOGY BACK-REACTION Granulite facies cordierite–garnet–biotite gneisses from the southeastern Reynolds Range, central Australia, contain both orthopyroxene-bearing and orthopyroxene-free quartzofeldspathic leucosomes. Mineral reaction microstructures at the interface of gneiss and leucosome observed in outcrop and petrographically, reflect melt-rock interaction during crystallization. Accessory monazite, susceptible to fluid alteration, dissolution and recrystallization at high temperature, is tested for its applicability to constrain the chemical and P–T–time evolution of melt-rock reactions during crystallization upon cooling. Bulk rock geochemistry and phase equilibria modelling constrain peak pressure and temperature conditions to 6.5–7.5 kbar and ~850°C, and U–Pb geochronology constrains the timing of monazite crystallization to 1.55 Ga, coeval with the Chewings Orogeny. Modelling predicts the presence of up to 15 vol.% melt at peak metamorphic conditions. Upon cooling below 800°C, melt extraction and in situ crystallization of melt decrease the melt volume to less than 7%, at which time it becomes entrapped and melt pockets induce replacement reactions in the adjacent host rock. Replacement reactions of garnet, orthopyroxene and K-feldspar liberate Y, REE, Eu and U in addition to Mg, Fe, Al, Si and K. We demonstrate that distinguishing between monazite varieties solely on the basis of U–Pb ages cannot solve the chronological order of events in this study, nor does it tie monazite to the evolution of melt or stability of rock-forming minerals. Rather, we argue that analyses of various internal monazite textures, their composition and overprinting relations allow us to identify the chronology of events following the metamorphic peak. We infer that retrograde reactions involving garnet, orthopyroxene and K-feldspar can be attributed to melt-rock interaction subsequent to partial melting, which is reflected in the development of compositionally distinct monazite textural domains. Internal monazite textures and their composition are consistent with dissolution and precipitation reactions induced by a high-T melt. Monazite rims enriched in Y, HREE, Eu and U indicate an increased availability of these elements, consistent with the breakdown of orthopyroxene, garnet and K-feldspar observed petrographically. Our study indicates that compositional and textural analysis of monazite in relation to major rock-forming minerals can be used to infer the post-peak chemical evolution of partial melts during high- to ultrahigh-temperature metamorphism. 2019 Journal Article 10.1111/jmg.12471 English https://unisa.alma.exlibrisgroup.com/view/delivery/61USOUTHAUS_INST/12174973280001831 http://purl.org/au-research/grants/arc/DP160103449 http://purl.org/au-research/grants/arc/LE150100013 WILEY restricted
spellingShingle Science & Technology
Physical Sciences
Geology
geochronology
granulite
melt-rock interaction
monazite
trace elements
GRANULITE-FACIES METAMORPHISM
SOUTHEASTERN REYNOLDS RANGE
CENTRAL AUSTRALIA
ARUNTA REGION
SHEAR ZONES
FLUID-FLOW
HIGH-T
HYDROTHERMAL ALTERATION
PB GEOCHRONOLOGY
BACK-REACTION
Prent, Alexander M.
Beinlich, Andreas
Morrissey, L.J.
Raimondo, T.
Clark, Chris
Putnis, Andrew
Monazite as a monitor for melt-rock interaction during cooling and exhumation
title Monazite as a monitor for melt-rock interaction during cooling and exhumation
title_full Monazite as a monitor for melt-rock interaction during cooling and exhumation
title_fullStr Monazite as a monitor for melt-rock interaction during cooling and exhumation
title_full_unstemmed Monazite as a monitor for melt-rock interaction during cooling and exhumation
title_short Monazite as a monitor for melt-rock interaction during cooling and exhumation
title_sort monazite as a monitor for melt-rock interaction during cooling and exhumation
topic Science & Technology
Physical Sciences
Geology
geochronology
granulite
melt-rock interaction
monazite
trace elements
GRANULITE-FACIES METAMORPHISM
SOUTHEASTERN REYNOLDS RANGE
CENTRAL AUSTRALIA
ARUNTA REGION
SHEAR ZONES
FLUID-FLOW
HIGH-T
HYDROTHERMAL ALTERATION
PB GEOCHRONOLOGY
BACK-REACTION
url https://unisa.alma.exlibrisgroup.com/view/delivery/61USOUTHAUS_INST/12174973280001831
https://unisa.alma.exlibrisgroup.com/view/delivery/61USOUTHAUS_INST/12174973280001831
https://unisa.alma.exlibrisgroup.com/view/delivery/61USOUTHAUS_INST/12174973280001831