Repeatable mechanical energy absorption of ZnO nanopillars

We show that repeatable energy absorption can be obtained via the reversible wurtzite-to-hexagonal phase transformation of ZnO nanopillars at room temperature. The effect is demonstrated using molecular dynamics simulations and available experimental data. With uniaxial compressive strains up to 22....

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Main Authors: Wang, J., Zhou, M., Yang, R., Xiao, P., Ke, F., Lu, Chunsheng
Format: Journal Article
Language:English
Published: ELSEVIER 2021
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/88298
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author Wang, J.
Zhou, M.
Yang, R.
Xiao, P.
Ke, F.
Lu, Chunsheng
author_facet Wang, J.
Zhou, M.
Yang, R.
Xiao, P.
Ke, F.
Lu, Chunsheng
author_sort Wang, J.
building Curtin Institutional Repository
collection Online Access
description We show that repeatable energy absorption can be obtained via the reversible wurtzite-to-hexagonal phase transformation of ZnO nanopillars at room temperature. The effect is demonstrated using molecular dynamics simulations and available experimental data. With uniaxial compressive strains up to 22.1% along the [0001] orientation, a ZnO nanopillar with a lateral dimension of 5.5 nm can produce average specific energy absorption on the order of 26.7 J g−1 under quasistatic cyclic loading and 11.1 J g−1 under rapid loading. The theoretical maximum of the specific energy absorption is 41.0 J g−1 which can be approached at nanopillars with lateral sizes above 55 nm. These values are comparable to that of widely used aluminum foams. The effects of inversion domain boundaries and sample size on the repeatable energy absorbing capacity are discussed. The findings open an avenue for ZnO nanostructures in mechanical energy absorption and dissipation applications.
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institution Curtin University Malaysia
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spelling curtin-20.500.11937-882982022-05-09T03:20:23Z Repeatable mechanical energy absorption of ZnO nanopillars Wang, J. Zhou, M. Yang, R. Xiao, P. Ke, F. Lu, Chunsheng Science & Technology Technology Materials Science, Multidisciplinary Materials Science ZnO nanopillars Repeatable energy absorption Phase transformation Inversion domain boundary Molecular dynamics INVERSION DOMAIN BOUNDARY MOLECULAR-DYNAMICS SIMULATION SYSTEMS We show that repeatable energy absorption can be obtained via the reversible wurtzite-to-hexagonal phase transformation of ZnO nanopillars at room temperature. The effect is demonstrated using molecular dynamics simulations and available experimental data. With uniaxial compressive strains up to 22.1% along the [0001] orientation, a ZnO nanopillar with a lateral dimension of 5.5 nm can produce average specific energy absorption on the order of 26.7 J g−1 under quasistatic cyclic loading and 11.1 J g−1 under rapid loading. The theoretical maximum of the specific energy absorption is 41.0 J g−1 which can be approached at nanopillars with lateral sizes above 55 nm. These values are comparable to that of widely used aluminum foams. The effects of inversion domain boundaries and sample size on the repeatable energy absorbing capacity are discussed. The findings open an avenue for ZnO nanostructures in mechanical energy absorption and dissipation applications. 2021 Journal Article http://hdl.handle.net/20.500.11937/88298 10.1016/j.mtcomm.2021.102904 English ELSEVIER restricted
spellingShingle Science & Technology
Technology
Materials Science, Multidisciplinary
Materials Science
ZnO nanopillars
Repeatable energy absorption
Phase transformation
Inversion domain boundary
Molecular dynamics
INVERSION DOMAIN BOUNDARY
MOLECULAR-DYNAMICS
SIMULATION
SYSTEMS
Wang, J.
Zhou, M.
Yang, R.
Xiao, P.
Ke, F.
Lu, Chunsheng
Repeatable mechanical energy absorption of ZnO nanopillars
title Repeatable mechanical energy absorption of ZnO nanopillars
title_full Repeatable mechanical energy absorption of ZnO nanopillars
title_fullStr Repeatable mechanical energy absorption of ZnO nanopillars
title_full_unstemmed Repeatable mechanical energy absorption of ZnO nanopillars
title_short Repeatable mechanical energy absorption of ZnO nanopillars
title_sort repeatable mechanical energy absorption of zno nanopillars
topic Science & Technology
Technology
Materials Science, Multidisciplinary
Materials Science
ZnO nanopillars
Repeatable energy absorption
Phase transformation
Inversion domain boundary
Molecular dynamics
INVERSION DOMAIN BOUNDARY
MOLECULAR-DYNAMICS
SIMULATION
SYSTEMS
url http://hdl.handle.net/20.500.11937/88298