Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments

In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application include materials such as poly(ionic liquid)s (PILs), ionic porous organic po...

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Main Authors: Jamil, Rabia, Tomé, L.C., Mecerreyes, D., Silvester-Dean, Debbie
Format: Journal Article
Published: 2021
Online Access:http://purl.org/au-research/grants/arc/FT170100315
http://hdl.handle.net/20.500.11937/88045
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author Jamil, Rabia
Tomé, L.C.
Mecerreyes, D.
Silvester-Dean, Debbie
author_facet Jamil, Rabia
Tomé, L.C.
Mecerreyes, D.
Silvester-Dean, Debbie
author_sort Jamil, Rabia
building Curtin Institutional Repository
collection Online Access
description In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application include materials such as poly(ionic liquid)s (PILs), ionic porous organic polymers (iPOPs) or ionic covalent organic frameworks (iCOFs) among others. All these organic materials share in common the ionic moiety cations such as imidazolium, pyridinium, viologen, ammonium, phosphonium, and guanidinium, and anions such as halides, [BF4]-, [PF6]-, and [Tf2N]-. The mechanistic aspects and efficiency of the CO2 conversion reaction and the polymer design including functional groups and porosity are discussed in detail. This review should provide valuable information for researchers to design new polymers for important catalysis applications.
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spelling curtin-20.500.11937-880452022-03-17T01:40:21Z Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments Jamil, Rabia Tomé, L.C. Mecerreyes, D. Silvester-Dean, Debbie In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application include materials such as poly(ionic liquid)s (PILs), ionic porous organic polymers (iPOPs) or ionic covalent organic frameworks (iCOFs) among others. All these organic materials share in common the ionic moiety cations such as imidazolium, pyridinium, viologen, ammonium, phosphonium, and guanidinium, and anions such as halides, [BF4]-, [PF6]-, and [Tf2N]-. The mechanistic aspects and efficiency of the CO2 conversion reaction and the polymer design including functional groups and porosity are discussed in detail. This review should provide valuable information for researchers to design new polymers for important catalysis applications. 2021 Journal Article http://hdl.handle.net/20.500.11937/88045 10.1071/CH21182 http://purl.org/au-research/grants/arc/FT170100315 http://creativecommons.org/licenses/by/4.0/ fulltext
spellingShingle Jamil, Rabia
Tomé, L.C.
Mecerreyes, D.
Silvester-Dean, Debbie
Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments
title Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments
title_full Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments
title_fullStr Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments
title_full_unstemmed Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments
title_short Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments
title_sort emerging ionic polymers for co2 conversion to cyclic carbonates: an overview of recent developments
url http://purl.org/au-research/grants/arc/FT170100315
http://hdl.handle.net/20.500.11937/88045