Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes
Syntheses of the bis-, tris- and tetra-tetrazolato calix[4]arene ligands were performed from their corresponding nitrile derivatives. Mono-nuclear lanthanoid complexes were characterised in the presence of triethylamine, while addition of aqueous ammonium acetate resulted in the formation of an unpr...
| Main Author: | |
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| Format: | Thesis |
| Language: | English |
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Curtin University
2015
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| Online Access: | 44708 http://hdl.handle.net/20.500.11937/853 |
| _version_ | 1848743499781898240 |
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| author | D'Alessio, Daniel Mark |
| author_facet | D'Alessio, Daniel Mark |
| author_sort | D'Alessio, Daniel Mark |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Syntheses of the bis-, tris- and tetra-tetrazolato calix[4]arene ligands were performed from their corresponding nitrile derivatives. Mono-nuclear lanthanoid complexes were characterised in the presence of triethylamine, while addition of aqueous ammonium acetate resulted in the formation of an unprecedented discrete linear nineteen lanthanoid hydroxo cluster (Ln19). It was found the length of the cluster could be altered to an Ln12 structure, while retaining an identical cluster motif, by simply replacing ammonium acetate with ammonium benzoate. |
| first_indexed | 2025-11-14T05:46:33Z |
| format | Thesis |
| id | curtin-20.500.11937-853 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T05:46:33Z |
| publishDate | 2015 |
| publisher | Curtin University |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-8532018-04-13T06:44:24Z Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes D'Alessio, Daniel Mark Syntheses of the bis-, tris- and tetra-tetrazolato calix[4]arene ligands were performed from their corresponding nitrile derivatives. Mono-nuclear lanthanoid complexes were characterised in the presence of triethylamine, while addition of aqueous ammonium acetate resulted in the formation of an unprecedented discrete linear nineteen lanthanoid hydroxo cluster (Ln19). It was found the length of the cluster could be altered to an Ln12 structure, while retaining an identical cluster motif, by simply replacing ammonium acetate with ammonium benzoate. 2015 Thesis http://hdl.handle.net/20.500.11937/853 en 44708 Curtin University fulltext |
| spellingShingle | D'Alessio, Daniel Mark Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes |
| title | Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes |
| title_full | Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes |
| title_fullStr | Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes |
| title_full_unstemmed | Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes |
| title_short | Lanthanoid complexes of tetrazolyl-functionalised Calix[4]arenes |
| title_sort | lanthanoid complexes of tetrazolyl-functionalised calix[4]arenes |
| url | 44708 http://hdl.handle.net/20.500.11937/853 |