Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal

This study deployed water-washing and dilute acid washing of a Victorian brown coal to prepare a set of coal samples with simplified occurrence forms of inorganic species. The resulted water-washed coal contains dominantly organically-bound species (primarily Mg, Ca, and Fe) and discrete mineral par...

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Main Authors: Gao, Xiangpeng, Rahim, Usman, Chen, Xixia, Wu, Hongwei
Format: Journal Article
Published: Elsevier Ltd 2014
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/8316
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author Gao, Xiangpeng
Rahim, Usman
Chen, Xixia
Wu, Hongwei
author_facet Gao, Xiangpeng
Rahim, Usman
Chen, Xixia
Wu, Hongwei
author_sort Gao, Xiangpeng
building Curtin Institutional Repository
collection Online Access
description This study deployed water-washing and dilute acid washing of a Victorian brown coal to prepare a set of coal samples with simplified occurrence forms of inorganic species. The resulted water-washed coal contains dominantly organically-bound species (primarily Mg, Ca, and Fe) and discrete mineral particles whereas the acid-washed coal only consists of discrete mineral particles. The coal samples (i.e., the raw, the water-washed and the acid-washed coals) were combusted in a lab-scale drop-tube furnace in air at 1400 °C to produce inorganic particulate matter (PM) with aerodynamic diameter less than 10 µm (PM10). Benchmarking on yields, particle size distribution, and chemical properties of PM10 produced from the combustion of the three coals clearly demonstrates that majority of PM10, including PM with aerodynamic diameter less than 1 µm (PM1) and between 1 and 10 µm (PM1–10), is contributed by organically-bound elements (mainly Mg, Ca, and Fe) whereas there is only limited contribution from discrete mineral particles due to their low contents in the brown coal. The results also clearly show that the water-soluble salts (e.g., NaCl) mainly contribute to the emission of PM with aerodynamic diameter less than 0.1 µm (PM0.1).
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spelling curtin-20.500.11937-83162017-09-13T14:37:52Z Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal Gao, Xiangpeng Rahim, Usman Chen, Xixia Wu, Hongwei PM10 Victorian brown coal Organically-bound inorganic species Combustion This study deployed water-washing and dilute acid washing of a Victorian brown coal to prepare a set of coal samples with simplified occurrence forms of inorganic species. The resulted water-washed coal contains dominantly organically-bound species (primarily Mg, Ca, and Fe) and discrete mineral particles whereas the acid-washed coal only consists of discrete mineral particles. The coal samples (i.e., the raw, the water-washed and the acid-washed coals) were combusted in a lab-scale drop-tube furnace in air at 1400 °C to produce inorganic particulate matter (PM) with aerodynamic diameter less than 10 µm (PM10). Benchmarking on yields, particle size distribution, and chemical properties of PM10 produced from the combustion of the three coals clearly demonstrates that majority of PM10, including PM with aerodynamic diameter less than 1 µm (PM1) and between 1 and 10 µm (PM1–10), is contributed by organically-bound elements (mainly Mg, Ca, and Fe) whereas there is only limited contribution from discrete mineral particles due to their low contents in the brown coal. The results also clearly show that the water-soluble salts (e.g., NaCl) mainly contribute to the emission of PM with aerodynamic diameter less than 0.1 µm (PM0.1). 2014 Journal Article http://hdl.handle.net/20.500.11937/8316 10.1016/j.fuel.2013.09.056 Elsevier Ltd restricted
spellingShingle PM10
Victorian brown coal
Organically-bound inorganic species
Combustion
Gao, Xiangpeng
Rahim, Usman
Chen, Xixia
Wu, Hongwei
Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal
title Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal
title_full Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal
title_fullStr Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal
title_full_unstemmed Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal
title_short Significant contribution of organically-bound Mg, Ca, and Fe to inorganic PM10 emission during the combustion of pulverized Victorian brown coal
title_sort significant contribution of organically-bound mg, ca, and fe to inorganic pm10 emission during the combustion of pulverized victorian brown coal
topic PM10
Victorian brown coal
Organically-bound inorganic species
Combustion
url http://hdl.handle.net/20.500.11937/8316