Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks

Vertical tube‐shaped iron‐oxide accumulations, named rusticles, obtained from the wrecks of the HMAS Sydney II and the HSK Kormoran at 2480 m ocean depth were chemically analysed along with surrounding seawater. Rusticles consisted of a porous aggregation of iron oxides and high levels of toxic meta...

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Main Authors: Silva‐Bedoya, Lina, Watkin, Elizabeth, Machuca Suarez, Laura
Format: Journal Article
Published: Wiley-Blackwell 2021
Online Access:http://hdl.handle.net/20.500.11937/83105
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author Silva‐Bedoya, Lina
Watkin, Elizabeth
Machuca Suarez, Laura
author_facet Silva‐Bedoya, Lina
Watkin, Elizabeth
Machuca Suarez, Laura
author_sort Silva‐Bedoya, Lina
building Curtin Institutional Repository
collection Online Access
description Vertical tube‐shaped iron‐oxide accumulations, named rusticles, obtained from the wrecks of the HMAS Sydney II and the HSK Kormoran at 2480 m ocean depth were chemically analysed along with surrounding seawater. Rusticles consisted of a porous aggregation of iron oxides and high levels of toxic metals and metalloids. Their growth rate is approximately 1 cm per year, predominantly over the areas of the hulls that remained underwater during their service years. A connection between the quality of antifouling paints and rusticle growth and composition was found. A mechanism explaining the formation of rusticles is proposed based on corrosion of carbon steel in deep‐seawater, water chemistry, surface complexation of iron oxides and chemical garden formation mechanisms. This study provides a complete rationalisation of the process of rusticle formation and deep‐water corrosion that is applicable to the long‐term integrity of offshore infrastructure.
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format Journal Article
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institution Curtin University Malaysia
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last_indexed 2025-11-14T11:21:15Z
publishDate 2021
publisher Wiley-Blackwell
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spelling curtin-20.500.11937-831052021-05-17T07:57:58Z Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks Silva‐Bedoya, Lina Watkin, Elizabeth Machuca Suarez, Laura Vertical tube‐shaped iron‐oxide accumulations, named rusticles, obtained from the wrecks of the HMAS Sydney II and the HSK Kormoran at 2480 m ocean depth were chemically analysed along with surrounding seawater. Rusticles consisted of a porous aggregation of iron oxides and high levels of toxic metals and metalloids. Their growth rate is approximately 1 cm per year, predominantly over the areas of the hulls that remained underwater during their service years. A connection between the quality of antifouling paints and rusticle growth and composition was found. A mechanism explaining the formation of rusticles is proposed based on corrosion of carbon steel in deep‐seawater, water chemistry, surface complexation of iron oxides and chemical garden formation mechanisms. This study provides a complete rationalisation of the process of rusticle formation and deep‐water corrosion that is applicable to the long‐term integrity of offshore infrastructure. 2021 Journal Article http://hdl.handle.net/20.500.11937/83105 10.1002/maco.202112289 Wiley-Blackwell restricted
spellingShingle Silva‐Bedoya, Lina
Watkin, Elizabeth
Machuca Suarez, Laura
Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks
title Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks
title_full Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks
title_fullStr Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks
title_full_unstemmed Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks
title_short Deep-Sea Corrosion Rusticles from Iron-Hulled Shipwrecks
title_sort deep-sea corrosion rusticles from iron-hulled shipwrecks
url http://hdl.handle.net/20.500.11937/83105