Aseismic refinement of orogenic gold systems

©2020 Society of Economic Geologists, Inc. Orogenic Au deposits have contributed the majority of Au recovered globally throughout history. However, the mechanism that concentrates Au to extremely high bonanza grades in small domains within these deposits remains enigmatic. The volume of fluid re...

Full description

Bibliographic Details
Main Authors: Voisey, C.R., Willis, D., Tomkins, A.G., Wilson, C.J.L., Micklethwaite, S., Salvemini, F., Bougoure, J., Rickard, William
Format: Journal Article
Language:English
Published: SOC ECONOMIC GEOLOGISTS, INC 2020
Subjects:
Online Access:http://purl.org/au-research/grants/arc/LP150100717
http://hdl.handle.net/20.500.11937/82053
_version_ 1848764466140807168
author Voisey, C.R.
Willis, D.
Tomkins, A.G.
Wilson, C.J.L.
Micklethwaite, S.
Salvemini, F.
Bougoure, J.
Rickard, William
author_facet Voisey, C.R.
Willis, D.
Tomkins, A.G.
Wilson, C.J.L.
Micklethwaite, S.
Salvemini, F.
Bougoure, J.
Rickard, William
author_sort Voisey, C.R.
building Curtin Institutional Repository
collection Online Access
description ©2020 Society of Economic Geologists, Inc. Orogenic Au deposits have contributed the majority of Au recovered globally throughout history. However, the mechanism that concentrates Au to extremely high bonanza grades in small domains within these deposits remains enigmatic. The volume of fluid required to provide extreme Au endowments in localized occurrences is not reflected in field observations (e.g., in the extent of quartz veining or hydrothermal alteration). Detailed optical, scanning and transmission electron microscopy, nanoscale secondary ion mass spectrometry, and 3-D neutron tomography have been used to investigate the processes responsible for development of anomalously high grade ore (upward of 3% Au) found in quartz veins at Fosterville gold mine (Victoria, Australia). Distinct textural settings of visible Au include (1) Au concentrated along pressure solution seams associated with wall-rock selvages, (2) as nano- to microscale dusty Au seams parallel to pressure solution seams, and (3) in microscale tension fractures perpendicular to stylolitic seams. The distribution of Au in arsenopyrite and pyrite hosted within pressure solution seams changes as a function of the extent of deformation. Sulfides in highly deformed pressure solution seams exclusively host Au as nano- to micrometer-sized clusters within features associated with corrosion and brittle failure, whereas sulfides in mildly deformed pressure solution seams have Au bound in the crystal structure. It is proposed that Au supersaturation in fluids introduced during seismic periods led to the deposition of abundant Au nanoparticles in quartz-carbonate veins. Subsequent pressure dissolution of vein quartz and carbonate during interseismic intervals allowed for episodic increase in the Au/ quartz ratio and permitted liberation and migration of Au nanoparticles, promoting Au grain growth in favorable textural settings. Galvanic corrosion and brittle fracturing of auriferous sulfides during the interseismic period allowed additional remobilization and/or enrichment of sulfide-hosted Au. Repetition of this mechanism over the time scale of deposit formation acted to concentrate Au within the lodes. This Au ore upgrading model, referred to as “aseismic refinement,” provides a new insight for the genesis of ultrarich Au mineralization and, based on textures reported from many Au deposits, may be a globally significant component in the formation of orogenic Au deposits.
first_indexed 2025-11-14T11:19:48Z
format Journal Article
id curtin-20.500.11937-82053
institution Curtin University Malaysia
institution_category Local University
language English
last_indexed 2025-11-14T11:19:48Z
publishDate 2020
publisher SOC ECONOMIC GEOLOGISTS, INC
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-820532021-03-09T01:05:49Z Aseismic refinement of orogenic gold systems Voisey, C.R. Willis, D. Tomkins, A.G. Wilson, C.J.L. Micklethwaite, S. Salvemini, F. Bougoure, J. Rickard, William Science & Technology Physical Sciences Geochemistry & Geophysics Mineralogy METAL NANOPARTICLES PRESSURE SOLUTION INVISIBLE GOLD LACHLAN OROGEN ARSENOPYRITE DEPOSIT PYRITE AUSTRALIA MINERALIZATION AGGREGATION ©2020 Society of Economic Geologists, Inc. Orogenic Au deposits have contributed the majority of Au recovered globally throughout history. However, the mechanism that concentrates Au to extremely high bonanza grades in small domains within these deposits remains enigmatic. The volume of fluid required to provide extreme Au endowments in localized occurrences is not reflected in field observations (e.g., in the extent of quartz veining or hydrothermal alteration). Detailed optical, scanning and transmission electron microscopy, nanoscale secondary ion mass spectrometry, and 3-D neutron tomography have been used to investigate the processes responsible for development of anomalously high grade ore (upward of 3% Au) found in quartz veins at Fosterville gold mine (Victoria, Australia). Distinct textural settings of visible Au include (1) Au concentrated along pressure solution seams associated with wall-rock selvages, (2) as nano- to microscale dusty Au seams parallel to pressure solution seams, and (3) in microscale tension fractures perpendicular to stylolitic seams. The distribution of Au in arsenopyrite and pyrite hosted within pressure solution seams changes as a function of the extent of deformation. Sulfides in highly deformed pressure solution seams exclusively host Au as nano- to micrometer-sized clusters within features associated with corrosion and brittle failure, whereas sulfides in mildly deformed pressure solution seams have Au bound in the crystal structure. It is proposed that Au supersaturation in fluids introduced during seismic periods led to the deposition of abundant Au nanoparticles in quartz-carbonate veins. Subsequent pressure dissolution of vein quartz and carbonate during interseismic intervals allowed for episodic increase in the Au/ quartz ratio and permitted liberation and migration of Au nanoparticles, promoting Au grain growth in favorable textural settings. Galvanic corrosion and brittle fracturing of auriferous sulfides during the interseismic period allowed additional remobilization and/or enrichment of sulfide-hosted Au. Repetition of this mechanism over the time scale of deposit formation acted to concentrate Au within the lodes. This Au ore upgrading model, referred to as “aseismic refinement,” provides a new insight for the genesis of ultrarich Au mineralization and, based on textures reported from many Au deposits, may be a globally significant component in the formation of orogenic Au deposits. 2020 Journal Article http://hdl.handle.net/20.500.11937/82053 10.5382/econgeo.4692 English http://purl.org/au-research/grants/arc/LP150100717 SOC ECONOMIC GEOLOGISTS, INC restricted
spellingShingle Science & Technology
Physical Sciences
Geochemistry & Geophysics
Mineralogy
METAL NANOPARTICLES
PRESSURE SOLUTION
INVISIBLE GOLD
LACHLAN OROGEN
ARSENOPYRITE
DEPOSIT
PYRITE
AUSTRALIA
MINERALIZATION
AGGREGATION
Voisey, C.R.
Willis, D.
Tomkins, A.G.
Wilson, C.J.L.
Micklethwaite, S.
Salvemini, F.
Bougoure, J.
Rickard, William
Aseismic refinement of orogenic gold systems
title Aseismic refinement of orogenic gold systems
title_full Aseismic refinement of orogenic gold systems
title_fullStr Aseismic refinement of orogenic gold systems
title_full_unstemmed Aseismic refinement of orogenic gold systems
title_short Aseismic refinement of orogenic gold systems
title_sort aseismic refinement of orogenic gold systems
topic Science & Technology
Physical Sciences
Geochemistry & Geophysics
Mineralogy
METAL NANOPARTICLES
PRESSURE SOLUTION
INVISIBLE GOLD
LACHLAN OROGEN
ARSENOPYRITE
DEPOSIT
PYRITE
AUSTRALIA
MINERALIZATION
AGGREGATION
url http://purl.org/au-research/grants/arc/LP150100717
http://hdl.handle.net/20.500.11937/82053