Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide
Problems arising from the extensive disorder characteristic of the crystalline lattice of dmso solvates of metal perchlorates at room temperature can in many cases be ameliorated or removed at "low" temperature. Present studies of several M(ClO4)n . 6dmso (n=2,3) species and Dy(ClO4)3 . 8d...
| Main Authors: | , , , , , |
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| Format: | Journal Article |
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Elsevier
2004
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| Online Access: | http://hdl.handle.net/20.500.11937/8074 |
| _version_ | 1848745550959083520 |
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| author | Chan, E. Cox, B. Harrowfield, J. Ogden, Mark Skelton, B. White, A. |
| author_facet | Chan, E. Cox, B. Harrowfield, J. Ogden, Mark Skelton, B. White, A. |
| author_sort | Chan, E. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Problems arising from the extensive disorder characteristic of the crystalline lattice of dmso solvates of metal perchlorates at room temperature can in many cases be ameliorated or removed at "low" temperature. Present studies of several M(ClO4)n . 6dmso (n=2,3) species and Dy(ClO4)3 . 8dmso have allowed detailed definition of several homoleptic dmso-solvated metal cations, all of which contain dmso as an O-bound unidentate ligand and which appear to closely confirm the forms of solvated cations deduced from independent solution studies. |
| first_indexed | 2025-11-14T06:19:09Z |
| format | Journal Article |
| id | curtin-20.500.11937-8074 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:19:09Z |
| publishDate | 2004 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-80742018-09-25T01:35:34Z Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide Chan, E. Cox, B. Harrowfield, J. Ogden, Mark Skelton, B. White, A. Homoleptic cation solvation Crystal structures Dmso complexes Problems arising from the extensive disorder characteristic of the crystalline lattice of dmso solvates of metal perchlorates at room temperature can in many cases be ameliorated or removed at "low" temperature. Present studies of several M(ClO4)n . 6dmso (n=2,3) species and Dy(ClO4)3 . 8dmso have allowed detailed definition of several homoleptic dmso-solvated metal cations, all of which contain dmso as an O-bound unidentate ligand and which appear to closely confirm the forms of solvated cations deduced from independent solution studies. 2004 Journal Article http://hdl.handle.net/20.500.11937/8074 10.1016/j.ica.2003.12.035 Elsevier restricted |
| spellingShingle | Homoleptic cation solvation Crystal structures Dmso complexes Chan, E. Cox, B. Harrowfield, J. Ogden, Mark Skelton, B. White, A. Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide |
| title | Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide |
| title_full | Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide |
| title_fullStr | Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide |
| title_full_unstemmed | Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide |
| title_short | Cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide |
| title_sort | cation solvation in the solid state - temperature-dependent crystal structures in some metal perchlorates solvated by dimethylsulfoxide |
| topic | Homoleptic cation solvation Crystal structures Dmso complexes |
| url | http://hdl.handle.net/20.500.11937/8074 |