Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes
© 2019 Informa UK Limited, trading as Taylor & Francis Group. Investigations into the distal-functionalisation of the phenols of racemic C4-symmetric tetramethoxyresorcinarene has led to a simple, single-step procedure that allows the isolation of gram quantities of partially silylated der...
| Main Authors: | , , |
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| Format: | Journal Article |
| Language: | English |
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TAYLOR & FRANCIS LTD
2019
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| Online Access: | http://hdl.handle.net/20.500.11937/80332 |
| _version_ | 1848764199940915200 |
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| author | Tan, Daniel Massera, C. Mocerino, Mauro |
| author_facet | Tan, Daniel Massera, C. Mocerino, Mauro |
| author_sort | Tan, Daniel |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © 2019 Informa UK Limited, trading as Taylor & Francis Group.
Investigations into the distal-functionalisation of the phenols of racemic C4-symmetric tetramethoxyresorcinarene has led to a simple, single-step procedure that allows the isolation of gram quantities of partially silylated derivatives, with the targeted distally silylated resorcinarene being obtained in a yield of 31%. These partially silylated derivatives would serve as versatile intermediates for the selective functionalisation of this elegant architecture. The solid-state structures of many of these derivatives have been determined by single crystal X-ray crystallography. |
| first_indexed | 2025-11-14T11:15:34Z |
| format | Journal Article |
| id | curtin-20.500.11937-80332 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T11:15:34Z |
| publishDate | 2019 |
| publisher | TAYLOR & FRANCIS LTD |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-803322020-10-12T02:46:48Z Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes Tan, Daniel Massera, C. Mocerino, Mauro Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry Resorcinarene calixarene axially chiral selective functionalisation CHIRAL CALIXARENES SYNTHESIS ENANTIOMERICALLY PURE RECOGNITION © 2019 Informa UK Limited, trading as Taylor & Francis Group. Investigations into the distal-functionalisation of the phenols of racemic C4-symmetric tetramethoxyresorcinarene has led to a simple, single-step procedure that allows the isolation of gram quantities of partially silylated derivatives, with the targeted distally silylated resorcinarene being obtained in a yield of 31%. These partially silylated derivatives would serve as versatile intermediates for the selective functionalisation of this elegant architecture. The solid-state structures of many of these derivatives have been determined by single crystal X-ray crystallography. 2019 Journal Article http://hdl.handle.net/20.500.11937/80332 10.1080/10610278.2019.1620949 English TAYLOR & FRANCIS LTD fulltext |
| spellingShingle | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry Resorcinarene calixarene axially chiral selective functionalisation CHIRAL CALIXARENES SYNTHESIS ENANTIOMERICALLY PURE RECOGNITION Tan, Daniel Massera, C. Mocerino, Mauro Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes |
| title | Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes |
| title_full | Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes |
| title_fullStr | Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes |
| title_full_unstemmed | Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes |
| title_short | Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes |
| title_sort | partial functionalisation of c4-symmetric tetramethoxyresorcinarenes |
| topic | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry Resorcinarene calixarene axially chiral selective functionalisation CHIRAL CALIXARENES SYNTHESIS ENANTIOMERICALLY PURE RECOGNITION |
| url | http://hdl.handle.net/20.500.11937/80332 |