Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns.
Our interest in the potential of chiral tetramethoxy-resorcinarene as agents for chiral recognition has led us to synthesise twelve distally-bridged chiral resorcinarene crowns. The fascinating architecture of these partially-enclosed chiral basket molecules is evident in the solid-state structures...
| Main Authors: | , , , |
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| Format: | Journal Article |
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Wiley-Blackwell
2020
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| Online Access: | http://hdl.handle.net/20.500.11937/80331 |
| _version_ | 1848764199694499840 |
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| author | Mocerino, Mauro Tan, Daniel A McIldowie, Matthew J Massera, Chiara |
| author_facet | Mocerino, Mauro Tan, Daniel A McIldowie, Matthew J Massera, Chiara |
| author_sort | Mocerino, Mauro |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Our interest in the potential of chiral tetramethoxy-resorcinarene as agents for chiral recognition has led us to synthesise twelve distally-bridged chiral resorcinarene crowns. The fascinating architecture of these partially-enclosed chiral basket molecules is evident in the solid-state structures which have been determined by single crystal X-ray crystallography. Moreover, the enantiomers of these chiral resorcinarene crowns have been resolved via diastereomeric resolution, with the absolute configuration of the diastereomers being determined by X-ray crystallography. This work enables further exploration of these enantio-pure chiral baskets as possible chiral resolving agents. |
| first_indexed | 2025-11-14T11:15:34Z |
| format | Journal Article |
| id | curtin-20.500.11937-80331 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T11:15:34Z |
| publishDate | 2020 |
| publisher | Wiley-Blackwell |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-803312020-12-17T07:09:29Z Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. Mocerino, Mauro Tan, Daniel A McIldowie, Matthew J Massera, Chiara 0305 - Organic Chemistry Our interest in the potential of chiral tetramethoxy-resorcinarene as agents for chiral recognition has led us to synthesise twelve distally-bridged chiral resorcinarene crowns. The fascinating architecture of these partially-enclosed chiral basket molecules is evident in the solid-state structures which have been determined by single crystal X-ray crystallography. Moreover, the enantiomers of these chiral resorcinarene crowns have been resolved via diastereomeric resolution, with the absolute configuration of the diastereomers being determined by X-ray crystallography. This work enables further exploration of these enantio-pure chiral baskets as possible chiral resolving agents. 2020 Journal Article http://hdl.handle.net/20.500.11937/80331 10.1002/ejoc.202000874 Wiley-Blackwell restricted |
| spellingShingle | 0305 - Organic Chemistry Mocerino, Mauro Tan, Daniel A McIldowie, Matthew J Massera, Chiara Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. |
| title | Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. |
| title_full | Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. |
| title_fullStr | Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. |
| title_full_unstemmed | Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. |
| title_short | Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns. |
| title_sort | synthesis of distally‐bridged chiral resorcinarene crowns. |
| topic | 0305 - Organic Chemistry |
| url | http://hdl.handle.net/20.500.11937/80331 |