Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2

Viscosity measurements of ten refrigerant mixtures were conducted in the homogeneous liquid and gas phases with a vibrating-wire viscometer in the temperature range from (233 to 373) K at pressures up to 10.0 MPa. The investigated mixtures include eight equimolar binaries (R32 + R125, R32 + R134a, R...

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Main Authors: Yang, Xiaoxian, Arami-Niya, Arash, Xiao, Xiong, Kim, Dongchan, Al Ghafri, Saif ZS, Tsuji, Tomoya, Tanaka, Yukio, Seiki, Yoshio, May, Eric F
Format: Journal Article
Published: American Chemical Society 2020
Online Access:http://hdl.handle.net/20.500.11937/79714
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author Yang, Xiaoxian
Arami-Niya, Arash
Xiao, Xiong
Kim, Dongchan
Al Ghafri, Saif ZS
Tsuji, Tomoya
Tanaka, Yukio
Seiki, Yoshio
May, Eric F
author_facet Yang, Xiaoxian
Arami-Niya, Arash
Xiao, Xiong
Kim, Dongchan
Al Ghafri, Saif ZS
Tsuji, Tomoya
Tanaka, Yukio
Seiki, Yoshio
May, Eric F
author_sort Yang, Xiaoxian
building Curtin Institutional Repository
collection Online Access
description Viscosity measurements of ten refrigerant mixtures were conducted in the homogeneous liquid and gas phases with a vibrating-wire viscometer in the temperature range from (233 to 373) K at pressures up to 10.0 MPa. The investigated mixtures include eight equimolar binaries (R32 + R125, R32 + R134a, R32 + CO2, R125 + R134a, R125 + CO2, R134a + R1234yf, R134a + CO2, and R1234yf + CO2) and two multicomponent mixtures (R32 + R1234yf + CO2 and R32 + R125 + R134a + R1234yf + CO2). The viscometer was calibrated with the measurements of pure carbon dioxide in both liquid and gas phases and verified with pure R32 and R125 measurements. The relative combined expanded uncertainties (k = 2) in the experimental viscosity are from (3.3 to 5.2) %. The relative deviations of the measured viscosities from values calculated with the extended corresponding states (ECS) model implemented in the REFPROP 10.0 software package were generally within 10%. The measured viscosities of binaries were used to tune the binary interaction parameters in the ECS model, and the model with the optimized parameters agreed with the experimental data of all investigated mixtures within 6% with significant improvements observed in the liquid phase.
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publishDate 2020
publisher American Chemical Society
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spelling curtin-20.500.11937-797142021-03-02T05:25:41Z Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2 Yang, Xiaoxian Arami-Niya, Arash Xiao, Xiong Kim, Dongchan Al Ghafri, Saif ZS Tsuji, Tomoya Tanaka, Yukio Seiki, Yoshio May, Eric F Viscosity measurements of ten refrigerant mixtures were conducted in the homogeneous liquid and gas phases with a vibrating-wire viscometer in the temperature range from (233 to 373) K at pressures up to 10.0 MPa. The investigated mixtures include eight equimolar binaries (R32 + R125, R32 + R134a, R32 + CO2, R125 + R134a, R125 + CO2, R134a + R1234yf, R134a + CO2, and R1234yf + CO2) and two multicomponent mixtures (R32 + R1234yf + CO2 and R32 + R125 + R134a + R1234yf + CO2). The viscometer was calibrated with the measurements of pure carbon dioxide in both liquid and gas phases and verified with pure R32 and R125 measurements. The relative combined expanded uncertainties (k = 2) in the experimental viscosity are from (3.3 to 5.2) %. The relative deviations of the measured viscosities from values calculated with the extended corresponding states (ECS) model implemented in the REFPROP 10.0 software package were generally within 10%. The measured viscosities of binaries were used to tune the binary interaction parameters in the ECS model, and the model with the optimized parameters agreed with the experimental data of all investigated mixtures within 6% with significant improvements observed in the liquid phase. 2020 Journal Article http://hdl.handle.net/20.500.11937/79714 American Chemical Society restricted
spellingShingle Yang, Xiaoxian
Arami-Niya, Arash
Xiao, Xiong
Kim, Dongchan
Al Ghafri, Saif ZS
Tsuji, Tomoya
Tanaka, Yukio
Seiki, Yoshio
May, Eric F
Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2
title Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2
title_full Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2
title_fullStr Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2
title_full_unstemmed Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2
title_short Viscosity Measurements of Binary and Multicomponent Refrigerant Mixtures Containing HFC-32, HFC-125, HFC-134a, HFO-1234yf, and CO2
title_sort viscosity measurements of binary and multicomponent refrigerant mixtures containing hfc-32, hfc-125, hfc-134a, hfo-1234yf, and co2
url http://hdl.handle.net/20.500.11937/79714