Etching of fission tracks in monazite: An experimental study

This study reports a range of etching and annealing experiments to establish the optimum conditions for the etching of fission tracks in monazite. The previously reported concentrated (12 M) HCl etchant at 90°C was found to cause grain loss from epoxy mounts and high degrees of grain corrosion, as d...

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Main Authors: Jones, S., Gleadow, A., Kohn, B., Reddy, Steven
Format: Journal Article
Language:English
Published: WILEY 2019
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/79369
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author Jones, S.
Gleadow, A.
Kohn, B.
Reddy, Steven
author_facet Jones, S.
Gleadow, A.
Kohn, B.
Reddy, Steven
author_sort Jones, S.
building Curtin Institutional Repository
collection Online Access
description This study reports a range of etching and annealing experiments to establish the optimum conditions for the etching of fission tracks in monazite. The previously reported concentrated (12 M) HCl etchant at 90°C was found to cause grain loss from epoxy mounts and high degrees of grain corrosion, as did much longer etching times at lower temperatures. Using implanted 252 Cf semi-tracks, a series of experiments were performed on internal prismatic faces of monazite-(Ce) crystals from the Palaeozoic Harcourt Granodiorite (Victoria, Australia) using an alternative 6 M HCl etchant, also at 90°C. Step-etch results show optimal etching at 60–90 min. Further, an isothermal annealing experiment illustrated that the degree of annealing that can be expected during etching at 90°C under laboratory time scales is negligible. The etching rate between grains is not uniform, with a correlation demonstrated between over-etched grains and high U and Th concentrations.
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spelling curtin-20.500.11937-793692020-07-07T00:40:26Z Etching of fission tracks in monazite: An experimental study Jones, S. Gleadow, A. Kohn, B. Reddy, Steven Science & Technology Physical Sciences Geosciences, Multidisciplinary Geology ZIRCON This study reports a range of etching and annealing experiments to establish the optimum conditions for the etching of fission tracks in monazite. The previously reported concentrated (12 M) HCl etchant at 90°C was found to cause grain loss from epoxy mounts and high degrees of grain corrosion, as did much longer etching times at lower temperatures. Using implanted 252 Cf semi-tracks, a series of experiments were performed on internal prismatic faces of monazite-(Ce) crystals from the Palaeozoic Harcourt Granodiorite (Victoria, Australia) using an alternative 6 M HCl etchant, also at 90°C. Step-etch results show optimal etching at 60–90 min. Further, an isothermal annealing experiment illustrated that the degree of annealing that can be expected during etching at 90°C under laboratory time scales is negligible. The etching rate between grains is not uniform, with a correlation demonstrated between over-etched grains and high U and Th concentrations. 2019 Journal Article http://hdl.handle.net/20.500.11937/79369 10.1111/ter.12382 English WILEY restricted
spellingShingle Science & Technology
Physical Sciences
Geosciences, Multidisciplinary
Geology
ZIRCON
Jones, S.
Gleadow, A.
Kohn, B.
Reddy, Steven
Etching of fission tracks in monazite: An experimental study
title Etching of fission tracks in monazite: An experimental study
title_full Etching of fission tracks in monazite: An experimental study
title_fullStr Etching of fission tracks in monazite: An experimental study
title_full_unstemmed Etching of fission tracks in monazite: An experimental study
title_short Etching of fission tracks in monazite: An experimental study
title_sort etching of fission tracks in monazite: an experimental study
topic Science & Technology
Physical Sciences
Geosciences, Multidisciplinary
Geology
ZIRCON
url http://hdl.handle.net/20.500.11937/79369