Shedding Light on the Structural and Luminescent Properties of Lanthanoid β-Triketonate Complexes

This thesis presents research centred around the structural and photophysical characterisation of ß-diketonate and ß-triketonate lanthanoid complexes. The overarching goal was to identify the effect of different co-ligands in lanthanoid complexes. 25 new complexes featuring six different ß-diketonat...

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Bibliographic Details
Main Author: Cameron, Lee John
Format: Thesis
Published: Curtin University 2019
Online Access:http://hdl.handle.net/20.500.11937/78465
Description
Summary:This thesis presents research centred around the structural and photophysical characterisation of ß-diketonate and ß-triketonate lanthanoid complexes. The overarching goal was to identify the effect of different co-ligands in lanthanoid complexes. 25 new complexes featuring six different ß-diketonate and ß-triketonate ligands, and four different co-ligands were isolated and characterised. The synthesis of a novel ß-triketonate molecule, bis-tribenzoylmethane, is presented, along with the first reported crystallographically characterised lanthanoid complex with bis-dibenzoylmethane coordinated.