Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion
Oil from the pyrolysis of biomass typically consists of two different layers defined as the aqueous and organic phases. The objective of this study was to determine the yield of liquid fuel that can be produced from the aqueous phase using a catalytic conversion. The process was supported by two dif...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Language: | English |
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AMER CHEMICAL SOC
2014
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| Subjects: | |
| Online Access: | http://hdl.handle.net/20.500.11937/78464 |
| _version_ | 1848763967629950976 |
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| author | Abnisa, F. Wan Daud, W.M.A. Arami-Niya, Arash Ali, B.S. Sahu, J.N. |
| author_facet | Abnisa, F. Wan Daud, W.M.A. Arami-Niya, Arash Ali, B.S. Sahu, J.N. |
| author_sort | Abnisa, F. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Oil from the pyrolysis of biomass typically consists of two different layers defined as the aqueous and organic phases. The objective of this study was to determine the yield of liquid fuel that can be produced from the aqueous phase using a catalytic conversion. The process was supported by two different HZSM-5 catalysts with temperatures set at 405, 455, 505, and 555 °C. The oils obtained were then analyzed using Karl Fischer titration, FTIR spectroscopy, GC/MS, TGA, and CHNS/O analysis. The results showed that the oil yields obtained from catalytic cracking of the aqueous phase ranged from 4 to 9.16 wt % depending on the catalyst type and temperature. The optimum performance of deoxygenation activity was obtained with the HZSM-5/50 catalyst at a temperature of 555 °C. The oil produced under the optimum conditions was dominated by aromatics and phenols and had an HHV of 38.44 MJ/kg. © 2014 American Chemical Society. |
| first_indexed | 2025-11-14T11:11:52Z |
| format | Journal Article |
| id | curtin-20.500.11937-78464 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T11:11:52Z |
| publishDate | 2014 |
| publisher | AMER CHEMICAL SOC |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-784642020-06-02T03:37:54Z Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion Abnisa, F. Wan Daud, W.M.A. Arami-Niya, Arash Ali, B.S. Sahu, J.N. Science & Technology Technology Energy & Fuels Engineering, Chemical Engineering BIO-OIL HZSM-5 ZEOLITE ACETIC-ACID BIOMASS GAS HYDROGEN EXTRACTION AROMATICS PRODUCTS BIOFUELS Oil from the pyrolysis of biomass typically consists of two different layers defined as the aqueous and organic phases. The objective of this study was to determine the yield of liquid fuel that can be produced from the aqueous phase using a catalytic conversion. The process was supported by two different HZSM-5 catalysts with temperatures set at 405, 455, 505, and 555 °C. The oils obtained were then analyzed using Karl Fischer titration, FTIR spectroscopy, GC/MS, TGA, and CHNS/O analysis. The results showed that the oil yields obtained from catalytic cracking of the aqueous phase ranged from 4 to 9.16 wt % depending on the catalyst type and temperature. The optimum performance of deoxygenation activity was obtained with the HZSM-5/50 catalyst at a temperature of 555 °C. The oil produced under the optimum conditions was dominated by aromatics and phenols and had an HHV of 38.44 MJ/kg. © 2014 American Chemical Society. 2014 Journal Article http://hdl.handle.net/20.500.11937/78464 10.1021/ef5003952 English AMER CHEMICAL SOC restricted |
| spellingShingle | Science & Technology Technology Energy & Fuels Engineering, Chemical Engineering BIO-OIL HZSM-5 ZEOLITE ACETIC-ACID BIOMASS GAS HYDROGEN EXTRACTION AROMATICS PRODUCTS BIOFUELS Abnisa, F. Wan Daud, W.M.A. Arami-Niya, Arash Ali, B.S. Sahu, J.N. Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion |
| title | Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion |
| title_full | Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion |
| title_fullStr | Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion |
| title_full_unstemmed | Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion |
| title_short | Recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion |
| title_sort | recovery of liquid fuel from the aqueous phase of pyrolysis oil using catalytic conversion |
| topic | Science & Technology Technology Energy & Fuels Engineering, Chemical Engineering BIO-OIL HZSM-5 ZEOLITE ACETIC-ACID BIOMASS GAS HYDROGEN EXTRACTION AROMATICS PRODUCTS BIOFUELS |
| url | http://hdl.handle.net/20.500.11937/78464 |