Modification of activated carbon using nitration followed by reduction for carbon dioxide capture

Activated carbon (AC) samples were modified using nitration followed by reduction to enhance their CO<inf>2</inf>adsorption capacities. Besides characterization of the samples, investigation of CO<inf>2</inf> capture performance was conducted by CO<inf>2</inf> iso...

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Main Authors: Shafeeyan, M.S., Houshmand, A., Arami-Niya, Arash, Razaghizadeh, H., Daud, W.M.A.W.
Format: Journal Article
Language:English
Published: WILEY-V C H VERLAG GMBH 2015
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/78463
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author Shafeeyan, M.S.
Houshmand, A.
Arami-Niya, Arash
Razaghizadeh, H.
Daud, W.M.A.W.
author_facet Shafeeyan, M.S.
Houshmand, A.
Arami-Niya, Arash
Razaghizadeh, H.
Daud, W.M.A.W.
author_sort Shafeeyan, M.S.
building Curtin Institutional Repository
collection Online Access
description Activated carbon (AC) samples were modified using nitration followed by reduction to enhance their CO<inf>2</inf>adsorption capacities. Besides characterization of the samples, investigation of CO<inf>2</inf> capture performance was conducted by CO<inf>2</inf> isothermal adsorption, temperature-programmed (TP) CO<inf>2</inf> adsorption, cyclic CO<inf>2</inf>adsorption-desorption, and dynamic CO<inf>2</inf> adsorption tests. Almost all modified samples showed a rise in the amount of CO<inf>2</inf> adsorbed when the comparison is made in unit surface area. On the other hand, some of the samples displayed a capacity superior to that of the parent material when compared in mass unit, especially at elevated temperatures. Despite ∼65% decrease in the surface area, TP-CO<inf>2</inf> adsorption of the best samples exhibited increases of ∼10 and 70% in CO<inf>2</inf> capture capacity at 30 and 100°C, respectively.
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publishDate 2015
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spelling curtin-20.500.11937-784632020-06-03T02:15:05Z Modification of activated carbon using nitration followed by reduction for carbon dioxide capture Shafeeyan, M.S. Houshmand, A. Arami-Niya, Arash Razaghizadeh, H. Daud, W.M.A.W. Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry Activated carbon Surface modification Anchoring Amino groups Nitration TEMPERATURE-PROGRAMMED DESORPTION CO2 CAPTURE SURFACE-CHEMISTRY POTENTIOMETRIC TITRATIONS GAS REMOVAL ADSORPTION AMINE SORBENTS ADSORBENTS WATER Activated carbon (AC) samples were modified using nitration followed by reduction to enhance their CO<inf>2</inf>adsorption capacities. Besides characterization of the samples, investigation of CO<inf>2</inf> capture performance was conducted by CO<inf>2</inf> isothermal adsorption, temperature-programmed (TP) CO<inf>2</inf> adsorption, cyclic CO<inf>2</inf>adsorption-desorption, and dynamic CO<inf>2</inf> adsorption tests. Almost all modified samples showed a rise in the amount of CO<inf>2</inf> adsorbed when the comparison is made in unit surface area. On the other hand, some of the samples displayed a capacity superior to that of the parent material when compared in mass unit, especially at elevated temperatures. Despite ∼65% decrease in the surface area, TP-CO<inf>2</inf> adsorption of the best samples exhibited increases of ∼10 and 70% in CO<inf>2</inf> capture capacity at 30 and 100°C, respectively. 2015 Journal Article http://hdl.handle.net/20.500.11937/78463 10.1002/bkcs.10100 English WILEY-V C H VERLAG GMBH restricted
spellingShingle Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
Activated carbon
Surface modification
Anchoring
Amino groups
Nitration
TEMPERATURE-PROGRAMMED DESORPTION
CO2 CAPTURE
SURFACE-CHEMISTRY
POTENTIOMETRIC TITRATIONS
GAS REMOVAL
ADSORPTION
AMINE
SORBENTS
ADSORBENTS
WATER
Shafeeyan, M.S.
Houshmand, A.
Arami-Niya, Arash
Razaghizadeh, H.
Daud, W.M.A.W.
Modification of activated carbon using nitration followed by reduction for carbon dioxide capture
title Modification of activated carbon using nitration followed by reduction for carbon dioxide capture
title_full Modification of activated carbon using nitration followed by reduction for carbon dioxide capture
title_fullStr Modification of activated carbon using nitration followed by reduction for carbon dioxide capture
title_full_unstemmed Modification of activated carbon using nitration followed by reduction for carbon dioxide capture
title_short Modification of activated carbon using nitration followed by reduction for carbon dioxide capture
title_sort modification of activated carbon using nitration followed by reduction for carbon dioxide capture
topic Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
Activated carbon
Surface modification
Anchoring
Amino groups
Nitration
TEMPERATURE-PROGRAMMED DESORPTION
CO2 CAPTURE
SURFACE-CHEMISTRY
POTENTIOMETRIC TITRATIONS
GAS REMOVAL
ADSORPTION
AMINE
SORBENTS
ADSORBENTS
WATER
url http://hdl.handle.net/20.500.11937/78463