Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends

This study investigates the phase behavior and fuel properties of a series of bio-oil/glycerol/methanol blends. The results show that even though glycerol has a poor solubility in bio-oil, homogeneous bio-oil/glycerol/methanol fuel blends can be prepared with appropriate amount of methanol addition....

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Main Authors: Zhang, Mingming, Wu, Hongwei
Format: Journal Article
Published: American Chemical Society 2014
Online Access:http://hdl.handle.net/20.500.11937/7842
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author Zhang, Mingming
Wu, Hongwei
author_facet Zhang, Mingming
Wu, Hongwei
author_sort Zhang, Mingming
building Curtin Institutional Repository
collection Online Access
description This study investigates the phase behavior and fuel properties of a series of bio-oil/glycerol/methanol blends. The results show that even though glycerol has a poor solubility in bio-oil, homogeneous bio-oil/glycerol/methanol fuel blends can be prepared with appropriate amount of methanol addition. Compared to the bio-oil or glycerol alone as a fuel, the bio-oil/glycerol/methanol blends have improved fuel properties (higher heating value, lower viscosity, and lower surface tension, etc.). Taking into safety consideration during storage and transportation of a fuel and the possible ratio of glycerol to methanol that may be obtained from biodiesel production process, potential feasible compositions of the bio-oil/glycerol/methanol blends (bio-oil ≥ 70 wt %; glycerol ≤ 20 wt %; methanol ≤ 10 wt %) are recommended as burner fuel for combustion applications. Further accelerated aging experiments of selected fuel blends in the recommended composition range indicate that the fuel blends experience decreases in the viscosity and total acid number and an increase in water content of the fuel blends upon long-term storage.
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spelling curtin-20.500.11937-78422017-09-13T16:05:52Z Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends Zhang, Mingming Wu, Hongwei This study investigates the phase behavior and fuel properties of a series of bio-oil/glycerol/methanol blends. The results show that even though glycerol has a poor solubility in bio-oil, homogeneous bio-oil/glycerol/methanol fuel blends can be prepared with appropriate amount of methanol addition. Compared to the bio-oil or glycerol alone as a fuel, the bio-oil/glycerol/methanol blends have improved fuel properties (higher heating value, lower viscosity, and lower surface tension, etc.). Taking into safety consideration during storage and transportation of a fuel and the possible ratio of glycerol to methanol that may be obtained from biodiesel production process, potential feasible compositions of the bio-oil/glycerol/methanol blends (bio-oil ≥ 70 wt %; glycerol ≤ 20 wt %; methanol ≤ 10 wt %) are recommended as burner fuel for combustion applications. Further accelerated aging experiments of selected fuel blends in the recommended composition range indicate that the fuel blends experience decreases in the viscosity and total acid number and an increase in water content of the fuel blends upon long-term storage. 2014 Journal Article http://hdl.handle.net/20.500.11937/7842 10.1021/ef501176z American Chemical Society unknown
spellingShingle Zhang, Mingming
Wu, Hongwei
Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends
title Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends
title_full Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends
title_fullStr Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends
title_full_unstemmed Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends
title_short Phase Behavior and Fuel Properties of Bio-Oil/Glycerol/Methanol Blends
title_sort phase behavior and fuel properties of bio-oil/glycerol/methanol blends
url http://hdl.handle.net/20.500.11937/7842