A (2-(naphthalen-2-yl)phenyl)rhodium(i) complex formed by a proposed intramolecular 1,4-: Ortho-To-ortho ′ Rh metal-Atom migration and its efficacy as an initiator in the controlled stereospecific polymerisation of phenylacetylene

A (2-(naphthalen-2-yl)phenyl)rhodium(i) complex formed by a proposed intramolecular 1,4-: Ortho-To-ortho ′ Rh metal-Atom migration and its efficacy as an initiator in the controlled stereospecific polymerisation of phenylacetylene

© The Royal Society of Chemistry. The synthesis of a novel Rh(i)-Aryl complex is detailed and its ability to serve as an initiator in the stereospecific polymerisation of phenylacetylene evaluated. Targeting the Rh(i) species, (2-phenylnaphthalen-1-yl)rhodium(i)(2,5-norbornadiene)tris(para-fluorophe...

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Bibliographic Details
Main Authors: Tan, N.S.L., Nealon, G.L., Lynam, J.M., Sobolev, A.N., Rowles, Matthew, Ogden, Mark, Massi, Max, Lowe, Andrew
Format: Journal Article
Language:English
Published: ROYAL SOC CHEMISTRY 2019
Subjects:
Science & Technology
Physical Sciences
Chemistry, Inorganic & Nuclear
Chemistry
SENSE-SELECTIVE POLYMERIZATION
BULKY ARYL ISOCYANIDE
AUXILIARY BASIS-SETS
LIVING POLYMERIZATION
GEOMETRY OPTIMIZATION
RHODIUM CATALYSTS
LIGAND
SHIFT
POLYACETYLENES
DERIVATIVES
Online Access:http://hdl.handle.net/20.500.11937/77878

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