Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones
© 2019 Elsevier Ltd This paper evaluates the feasibility of using fusion waste chicken and fish bones as the reusable and low cost solid catalyst for synthesis of biodiesel from used cooking oil via two-step transesterification. A catalyst characterization of the prepared fusion waste chicken and fi...
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| Format: | Journal Article |
| Language: | English |
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PERGAMON-ELSEVIER SCIENCE LTD
2019
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| Online Access: | http://hdl.handle.net/20.500.11937/77489 |
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| author | Tan, Yie Hua Abdullah, M.O. Kansedo, Jibrail Mujawar, Mubarak Chan, Stephanie Nolasco-Hipolito, C. |
| author_facet | Tan, Yie Hua Abdullah, M.O. Kansedo, Jibrail Mujawar, Mubarak Chan, Stephanie Nolasco-Hipolito, C. |
| author_sort | Tan, Yie Hua |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © 2019 Elsevier Ltd This paper evaluates the feasibility of using fusion waste chicken and fish bones as the reusable and low cost solid catalyst for synthesis of biodiesel from used cooking oil via two-step transesterification. A catalyst characterization of the prepared fusion waste chicken and fish bones catalyst was made in order to study their catalytic performance through various techniques such as Scanning Electron Microscopy (SEM), Brunauer–Emmett–Teller (BET), Particle Size Analysis (PSA), Thermal Gravimetric Analysis (TGA), Fourier Transform Infrared spectra (FTIR), Carbon Dioxide-Temperature Programmed Desorption (TPD-CO2) and X-Ray Diffraction (XRD). The used cooking oil transesterification was optimized using a response surface methodology (RSM) based on five level three variables central composite design (CCD). The RSM results revealed that the optimal operational condition for the transesterification has defined as: catalyst loading, 1.98%w/v, reaction temperature, 65 °C and time, 1.54 h, whereas the alcohol/oil molar ratio, 10:1 is a fixed variable in this study. The actual biodiesel yield of 89.5% was achieved under the predicted optimal conditions and fulfilled the ASTM D6751 biodiesel fuel standards. The promising features of the chicken and fish bones catalyst are inexpensive, easily obtained, simple work-up, simple recovery, reusability without significant drop in catalytic activity for up to four consecutive runs. |
| first_indexed | 2025-11-14T11:10:05Z |
| format | Journal Article |
| id | curtin-20.500.11937-77489 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T11:10:05Z |
| publishDate | 2019 |
| publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-774892020-02-25T02:23:26Z Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones Tan, Yie Hua Abdullah, M.O. Kansedo, Jibrail Mujawar, Mubarak Chan, Stephanie Nolasco-Hipolito, C. Science & Technology Technology Green & Sustainable Science & Technology Energy & Fuels Science & Technology - Other Topics Biodiesel production Heterogeneous catalyst Chicken bone Fish bone HETEROGENEOUS CATALYST PALM OIL SHELL TRANSESTERIFICATION CAO OPTIMIZATION EGGSHELLS JATROPHA OSTRICH © 2019 Elsevier Ltd This paper evaluates the feasibility of using fusion waste chicken and fish bones as the reusable and low cost solid catalyst for synthesis of biodiesel from used cooking oil via two-step transesterification. A catalyst characterization of the prepared fusion waste chicken and fish bones catalyst was made in order to study their catalytic performance through various techniques such as Scanning Electron Microscopy (SEM), Brunauer–Emmett–Teller (BET), Particle Size Analysis (PSA), Thermal Gravimetric Analysis (TGA), Fourier Transform Infrared spectra (FTIR), Carbon Dioxide-Temperature Programmed Desorption (TPD-CO2) and X-Ray Diffraction (XRD). The used cooking oil transesterification was optimized using a response surface methodology (RSM) based on five level three variables central composite design (CCD). The RSM results revealed that the optimal operational condition for the transesterification has defined as: catalyst loading, 1.98%w/v, reaction temperature, 65 °C and time, 1.54 h, whereas the alcohol/oil molar ratio, 10:1 is a fixed variable in this study. The actual biodiesel yield of 89.5% was achieved under the predicted optimal conditions and fulfilled the ASTM D6751 biodiesel fuel standards. The promising features of the chicken and fish bones catalyst are inexpensive, easily obtained, simple work-up, simple recovery, reusability without significant drop in catalytic activity for up to four consecutive runs. 2019 Journal Article http://hdl.handle.net/20.500.11937/77489 10.1016/j.renene.2019.02.110 English PERGAMON-ELSEVIER SCIENCE LTD restricted |
| spellingShingle | Science & Technology Technology Green & Sustainable Science & Technology Energy & Fuels Science & Technology - Other Topics Biodiesel production Heterogeneous catalyst Chicken bone Fish bone HETEROGENEOUS CATALYST PALM OIL SHELL TRANSESTERIFICATION CAO OPTIMIZATION EGGSHELLS JATROPHA OSTRICH Tan, Yie Hua Abdullah, M.O. Kansedo, Jibrail Mujawar, Mubarak Chan, Stephanie Nolasco-Hipolito, C. Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones |
| title | Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones |
| title_full | Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones |
| title_fullStr | Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones |
| title_full_unstemmed | Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones |
| title_short | Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones |
| title_sort | biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones |
| topic | Science & Technology Technology Green & Sustainable Science & Technology Energy & Fuels Science & Technology - Other Topics Biodiesel production Heterogeneous catalyst Chicken bone Fish bone HETEROGENEOUS CATALYST PALM OIL SHELL TRANSESTERIFICATION CAO OPTIMIZATION EGGSHELLS JATROPHA OSTRICH |
| url | http://hdl.handle.net/20.500.11937/77489 |