Metal coordination with an amide-functionalized axially chiral resorcinarene
The synthesis and characterization of an amide-functionalized axially chiral resorcinarene, 14,36,56,76-tetra-2-oxo-2-(2-hydroxyethylamino)ethoxy-16,34,54,74-tetramethoxy-2,4,6,8- tetrapropylresorcin[4]arene, is reported. Metal complexation with picrate salts gave crystalline products that could be...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Language: | English |
| Published: |
SPRINGER
2019
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| Subjects: | |
| Online Access: | http://hdl.handle.net/20.500.11937/76622 |
| _version_ | 1848763732733198336 |
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| author | Vaughan, Jamila Bertata, Munna Ali Mohamed Skelton, B.W. Ogden, Mark Mocerino, Mauro |
| author_facet | Vaughan, Jamila Bertata, Munna Ali Mohamed Skelton, B.W. Ogden, Mark Mocerino, Mauro |
| author_sort | Vaughan, Jamila |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The synthesis and characterization of an amide-functionalized axially chiral resorcinarene, 14,36,56,76-tetra-2-oxo-2-(2-hydroxyethylamino)ethoxy-16,34,54,74-tetramethoxy-2,4,6,8- tetrapropylresorcin[4]arene, is reported. Metal complexation with picrate salts gave crystalline products that could be structurally characterised for calcium, lanthanum, praseodymium, and ytterbium. While the details of these structures vary, the metal–ligand interactions are remarkably consistent, with coordination polymers formed through interaction between three of the amide O atoms, each binding to a different metal atom. No other potential donor atom of the macrocycle is bound to the metal atoms, with the coordination spheres completed by solvent or picrate donor O atoms. |
| first_indexed | 2025-11-14T11:08:08Z |
| format | Journal Article |
| id | curtin-20.500.11937-76622 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| language | English |
| last_indexed | 2025-11-14T11:08:08Z |
| publishDate | 2019 |
| publisher | SPRINGER |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-766222020-06-02T00:39:54Z Metal coordination with an amide-functionalized axially chiral resorcinarene Vaughan, Jamila Bertata, Munna Ali Mohamed Skelton, B.W. Ogden, Mark Mocerino, Mauro Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry Resorcinarene Lanthanide Picrate Crystal structure RARE-EARTH COMPLEXES CRYSTAL-STRUCTURE STRUCTURAL-CHARACTERIZATION SYSTEMATICS The synthesis and characterization of an amide-functionalized axially chiral resorcinarene, 14,36,56,76-tetra-2-oxo-2-(2-hydroxyethylamino)ethoxy-16,34,54,74-tetramethoxy-2,4,6,8- tetrapropylresorcin[4]arene, is reported. Metal complexation with picrate salts gave crystalline products that could be structurally characterised for calcium, lanthanum, praseodymium, and ytterbium. While the details of these structures vary, the metal–ligand interactions are remarkably consistent, with coordination polymers formed through interaction between three of the amide O atoms, each binding to a different metal atom. No other potential donor atom of the macrocycle is bound to the metal atoms, with the coordination spheres completed by solvent or picrate donor O atoms. 2019 Journal Article http://hdl.handle.net/20.500.11937/76622 10.1007/s10847-019-00922-w English SPRINGER fulltext |
| spellingShingle | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry Resorcinarene Lanthanide Picrate Crystal structure RARE-EARTH COMPLEXES CRYSTAL-STRUCTURE STRUCTURAL-CHARACTERIZATION SYSTEMATICS Vaughan, Jamila Bertata, Munna Ali Mohamed Skelton, B.W. Ogden, Mark Mocerino, Mauro Metal coordination with an amide-functionalized axially chiral resorcinarene |
| title | Metal coordination with an amide-functionalized axially chiral resorcinarene |
| title_full | Metal coordination with an amide-functionalized axially chiral resorcinarene |
| title_fullStr | Metal coordination with an amide-functionalized axially chiral resorcinarene |
| title_full_unstemmed | Metal coordination with an amide-functionalized axially chiral resorcinarene |
| title_short | Metal coordination with an amide-functionalized axially chiral resorcinarene |
| title_sort | metal coordination with an amide-functionalized axially chiral resorcinarene |
| topic | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry Resorcinarene Lanthanide Picrate Crystal structure RARE-EARTH COMPLEXES CRYSTAL-STRUCTURE STRUCTURAL-CHARACTERIZATION SYSTEMATICS |
| url | http://hdl.handle.net/20.500.11937/76622 |