Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia

Large deep caves with little relation to surface topography are distinctive karst features on the Nullarbor Plain of Australia. The presence of gypsum deposits and chemoautotrophic bacteria within the caves have been suggested as evidence for cave formation and (or) enlargement via sulfuric acid spe...

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Main Authors: Lipar, M., Ferk, M., Lojen, S., Barham, Milo
Format: Journal Article
Published: Società Speleologica Italiana 2019
Online Access:http://hdl.handle.net/20.500.11937/76475
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author Lipar, M.
Ferk, M.
Lojen, S.
Barham, Milo
author_facet Lipar, M.
Ferk, M.
Lojen, S.
Barham, Milo
author_sort Lipar, M.
building Curtin Institutional Repository
collection Online Access
description Large deep caves with little relation to surface topography are distinctive karst features on the Nullarbor Plain of Australia. The presence of gypsum deposits and chemoautotrophic bacteria within the caves have been suggested as evidence for cave formation and (or) enlargement via sulfuric acid speleogenesis. To test this hypothesis, the stable sulfur isotope compositions (δ34S) of both cave gypsum and surface gypsum were measured. Analyses yielded relatively high, positive δ34S values from both cave gypsum and surface gypsum, arguing against gypsum genesis via microbial chemoautotrophy, and more broadly, sulfuric acid speleogenesis. Instead, the gypsum is interpreted as forming via evaporation of seawater during the Quaternary.
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format Journal Article
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institution Curtin University Malaysia
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publishDate 2019
publisher Società Speleologica Italiana
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spelling curtin-20.500.11937-764752019-10-11T03:48:08Z Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia Lipar, M. Ferk, M. Lojen, S. Barham, Milo Large deep caves with little relation to surface topography are distinctive karst features on the Nullarbor Plain of Australia. The presence of gypsum deposits and chemoautotrophic bacteria within the caves have been suggested as evidence for cave formation and (or) enlargement via sulfuric acid speleogenesis. To test this hypothesis, the stable sulfur isotope compositions (δ34S) of both cave gypsum and surface gypsum were measured. Analyses yielded relatively high, positive δ34S values from both cave gypsum and surface gypsum, arguing against gypsum genesis via microbial chemoautotrophy, and more broadly, sulfuric acid speleogenesis. Instead, the gypsum is interpreted as forming via evaporation of seawater during the Quaternary. 2019 Journal Article http://hdl.handle.net/20.500.11937/76475 10.5038/1827-806X.48.1.2196 https://creativecommons.org/licenses/by-nc/4.0/ Società Speleologica Italiana fulltext
spellingShingle Lipar, M.
Ferk, M.
Lojen, S.
Barham, Milo
Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia
title Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia
title_full Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia
title_fullStr Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia
title_full_unstemmed Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia
title_short Sulfur (³⁴S/³²S) isotope composition of gypsum and implications for deep cave formation on the Nullarbor Plain, Australia
title_sort sulfur (³⁴s/³²s) isotope composition of gypsum and implications for deep cave formation on the nullarbor plain, australia
url http://hdl.handle.net/20.500.11937/76475