Pb-isotopic evidence for an early, enriched crust on Mars

Martian meteorite NWA 7533 is a regolith breccia that compositionally resembles the Martian surface measured by orbiters and landers. NWA 7533 contains monzonitic clasts that have zircon with U–Pb ages of 4.428 Ga. The Pb isotopic compositions of plagioclase and alkali feldspars, as well as U–Pb iso...

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Main Authors: Nemchin, Alexander, Bellucci, J., Whitehouse, M., Humayum, M., Hewins, R., Zanda, B.
Format: Journal Article
Published: Elsevier Science BV 2014
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/7621
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author Nemchin, Alexander
Bellucci, J.
Whitehouse, M.
Humayum, M.
Hewins, R.
Zanda, B.
author_facet Nemchin, Alexander
Bellucci, J.
Whitehouse, M.
Humayum, M.
Hewins, R.
Zanda, B.
author_sort Nemchin, Alexander
building Curtin Institutional Repository
collection Online Access
description Martian meteorite NWA 7533 is a regolith breccia that compositionally resembles the Martian surface measured by orbiters and landers. NWA 7533 contains monzonitic clasts that have zircon with U–Pb ages of 4.428 Ga. The Pb isotopic compositions of plagioclase and alkali feldspars, as well as U–Pb isotopic compositions of chlorapatite in the monzonitic clasts of NWA 7533 have been measured by Secondary Ion Mass Spectrometry (SIMS). The U–Pb isotopic compositions measured from the chlorapatite in NWA 7533 yield an age of 1.357 ±81Ga (2σ). The least radiogenic Pb isotopic compositions measured in plagioclase and K-feldspar lie within error of the 4.428 Ga Geochron. These data indicate that the monzonitic clasts in NWA 7533 are a product of a differentiation history that includes residence in a reservoir that formed prior to 4.428 Ga with a µ-value (238U/204Pb) of at least 13.4 ±1.7 (2σ) and a k-value (232Th/238U) of ~4.3. This µ-value is more than three times higher than any other documented Martian reservoir. These results indicate either the Martian mantle is significantly more heterogeneous than previously thought (µ-value of 1–14 vs. 1–5) and/or the monzonitic clasts formed by the melting of Martian crust with a µ-value of at least 13.4. Therefore, NWA 7533 may contain the first isotopic evidence for an enriched, differentiated crust on Mars.
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spelling curtin-20.500.11937-76212017-09-13T14:37:53Z Pb-isotopic evidence for an early, enriched crust on Mars Nemchin, Alexander Bellucci, J. Whitehouse, M. Humayum, M. Hewins, R. Zanda, B. Martian crust Pb isotopes Martian geochemistry Mars NWA 7533 Black Beauty Martian meteorite NWA 7533 is a regolith breccia that compositionally resembles the Martian surface measured by orbiters and landers. NWA 7533 contains monzonitic clasts that have zircon with U–Pb ages of 4.428 Ga. The Pb isotopic compositions of plagioclase and alkali feldspars, as well as U–Pb isotopic compositions of chlorapatite in the monzonitic clasts of NWA 7533 have been measured by Secondary Ion Mass Spectrometry (SIMS). The U–Pb isotopic compositions measured from the chlorapatite in NWA 7533 yield an age of 1.357 ±81Ga (2σ). The least radiogenic Pb isotopic compositions measured in plagioclase and K-feldspar lie within error of the 4.428 Ga Geochron. These data indicate that the monzonitic clasts in NWA 7533 are a product of a differentiation history that includes residence in a reservoir that formed prior to 4.428 Ga with a µ-value (238U/204Pb) of at least 13.4 ±1.7 (2σ) and a k-value (232Th/238U) of ~4.3. This µ-value is more than three times higher than any other documented Martian reservoir. These results indicate either the Martian mantle is significantly more heterogeneous than previously thought (µ-value of 1–14 vs. 1–5) and/or the monzonitic clasts formed by the melting of Martian crust with a µ-value of at least 13.4. Therefore, NWA 7533 may contain the first isotopic evidence for an enriched, differentiated crust on Mars. 2014 Journal Article http://hdl.handle.net/20.500.11937/7621 10.1016/j.epsl.2014.11.018 Elsevier Science BV unknown
spellingShingle Martian crust
Pb isotopes
Martian geochemistry
Mars
NWA 7533
Black Beauty
Nemchin, Alexander
Bellucci, J.
Whitehouse, M.
Humayum, M.
Hewins, R.
Zanda, B.
Pb-isotopic evidence for an early, enriched crust on Mars
title Pb-isotopic evidence for an early, enriched crust on Mars
title_full Pb-isotopic evidence for an early, enriched crust on Mars
title_fullStr Pb-isotopic evidence for an early, enriched crust on Mars
title_full_unstemmed Pb-isotopic evidence for an early, enriched crust on Mars
title_short Pb-isotopic evidence for an early, enriched crust on Mars
title_sort pb-isotopic evidence for an early, enriched crust on mars
topic Martian crust
Pb isotopes
Martian geochemistry
Mars
NWA 7533
Black Beauty
url http://hdl.handle.net/20.500.11937/7621