Single vs mixed organic cation for low temperature processed perovskite solar cells

The present work reports a comparative study between single and mixed organic cation based MAPbI3 and MA0.6FA0.4PbI3 perovskite devices fabricated in conjunction with low temperature processed (<150 °C) ZnO electron transport layers. MA0.6FA0.4PbI3 perovskite devices demonstrate 37% higher power...

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Main Authors: Mahmud, M., Elumalai, Naveen Kumar, Upama, M., Wang, D., Wright, M., Chan, K., Xu, C., Haque, F., Uddin, A.
Format: Journal Article
Published: Pergamon 2016
Online Access:http://hdl.handle.net/20.500.11937/74870
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author Mahmud, M.
Elumalai, Naveen Kumar
Upama, M.
Wang, D.
Wright, M.
Chan, K.
Xu, C.
Haque, F.
Uddin, A.
author_facet Mahmud, M.
Elumalai, Naveen Kumar
Upama, M.
Wang, D.
Wright, M.
Chan, K.
Xu, C.
Haque, F.
Uddin, A.
author_sort Mahmud, M.
building Curtin Institutional Repository
collection Online Access
description The present work reports a comparative study between single and mixed organic cation based MAPbI3 and MA0.6FA0.4PbI3 perovskite devices fabricated in conjunction with low temperature processed (<150 °C) ZnO electron transport layers. MA0.6FA0.4PbI3 perovskite devices demonstrate 37% higher power conversion efficiency compared to MAPbI3 perovskite devices developed on the ZnO ETL. In addition, MA0.6FA0.4PbI3 devices exhibit very low photocurrent hysteresis and they are three-fold more stable than conventional MAPbI3 PSCs (perovskite solar cells). An in-depth analysis on the charge transport properties in both fresh and aged devices has been carried out using electrochemical impedance spectroscopy analysis to comprehend the enhanced device stability of the mixed perovskite devices developed on the ZnO ETL. The study also investigates into the interfacial charge transfer characteristics associated with the ZnO/mixed organic cation perovskite interface and concomitant influence on the inherent electronic properties.
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format Journal Article
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T11:02:48Z
publishDate 2016
publisher Pergamon
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spelling curtin-20.500.11937-748702019-06-26T08:08:59Z Single vs mixed organic cation for low temperature processed perovskite solar cells Mahmud, M. Elumalai, Naveen Kumar Upama, M. Wang, D. Wright, M. Chan, K. Xu, C. Haque, F. Uddin, A. The present work reports a comparative study between single and mixed organic cation based MAPbI3 and MA0.6FA0.4PbI3 perovskite devices fabricated in conjunction with low temperature processed (<150 °C) ZnO electron transport layers. MA0.6FA0.4PbI3 perovskite devices demonstrate 37% higher power conversion efficiency compared to MAPbI3 perovskite devices developed on the ZnO ETL. In addition, MA0.6FA0.4PbI3 devices exhibit very low photocurrent hysteresis and they are three-fold more stable than conventional MAPbI3 PSCs (perovskite solar cells). An in-depth analysis on the charge transport properties in both fresh and aged devices has been carried out using electrochemical impedance spectroscopy analysis to comprehend the enhanced device stability of the mixed perovskite devices developed on the ZnO ETL. The study also investigates into the interfacial charge transfer characteristics associated with the ZnO/mixed organic cation perovskite interface and concomitant influence on the inherent electronic properties. 2016 Journal Article http://hdl.handle.net/20.500.11937/74870 10.1016/j.electacta.2016.11.132 Pergamon restricted
spellingShingle Mahmud, M.
Elumalai, Naveen Kumar
Upama, M.
Wang, D.
Wright, M.
Chan, K.
Xu, C.
Haque, F.
Uddin, A.
Single vs mixed organic cation for low temperature processed perovskite solar cells
title Single vs mixed organic cation for low temperature processed perovskite solar cells
title_full Single vs mixed organic cation for low temperature processed perovskite solar cells
title_fullStr Single vs mixed organic cation for low temperature processed perovskite solar cells
title_full_unstemmed Single vs mixed organic cation for low temperature processed perovskite solar cells
title_short Single vs mixed organic cation for low temperature processed perovskite solar cells
title_sort single vs mixed organic cation for low temperature processed perovskite solar cells
url http://hdl.handle.net/20.500.11937/74870