Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode

© 2018 American Chemical Society. In recent years, a rechargeable aluminum-ion battery based on ionic liquid electrolyte is being extensively explored due to three-electron electrochemical reactions, rich resources, and safety. Herein, a rechargeable Al-ion battery composed of MoS2microsphere cathod...

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Main Authors: Li, Z., Niu, B., Liu, Jian, Li, J., Kang, F.
Format: Journal Article
Published: American Chemical Society 2018
Online Access:http://hdl.handle.net/20.500.11937/73438
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author Li, Z.
Niu, B.
Liu, Jian
Li, J.
Kang, F.
author_facet Li, Z.
Niu, B.
Liu, Jian
Li, J.
Kang, F.
author_sort Li, Z.
building Curtin Institutional Repository
collection Online Access
description © 2018 American Chemical Society. In recent years, a rechargeable aluminum-ion battery based on ionic liquid electrolyte is being extensively explored due to three-electron electrochemical reactions, rich resources, and safety. Herein, a rechargeable Al-ion battery composed of MoS2microsphere cathode, aluminum anode, and ionic liquid electrolyte has been fabricated for the first time. It can be found that Al3+intercalates into the MoS2during the electrochemical reaction, whereas the storage mechanisms of the electrode material interface and internal are quite different. This result is confirmed by ex situ X-ray photoelectron spectroscopy and X-ray diffraction etching techniques. Meanwhile, this aluminum-ion battery also shows excellent electrochemical performance, such as a discharge specific capacity of 253.6 mA h g-1at a current density of 20 mA g-1and a discharge capacity of 66.7 mA h g-1at a current density of 40 mA g-1after 100 cycles. This will lay a solid foundation for the commercialization of aluminum-ion batteries.
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institution Curtin University Malaysia
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publishDate 2018
publisher American Chemical Society
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spelling curtin-20.500.11937-734382023-08-02T06:39:13Z Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode Li, Z. Niu, B. Liu, Jian Li, J. Kang, F. © 2018 American Chemical Society. In recent years, a rechargeable aluminum-ion battery based on ionic liquid electrolyte is being extensively explored due to three-electron electrochemical reactions, rich resources, and safety. Herein, a rechargeable Al-ion battery composed of MoS2microsphere cathode, aluminum anode, and ionic liquid electrolyte has been fabricated for the first time. It can be found that Al3+intercalates into the MoS2during the electrochemical reaction, whereas the storage mechanisms of the electrode material interface and internal are quite different. This result is confirmed by ex situ X-ray photoelectron spectroscopy and X-ray diffraction etching techniques. Meanwhile, this aluminum-ion battery also shows excellent electrochemical performance, such as a discharge specific capacity of 253.6 mA h g-1at a current density of 20 mA g-1and a discharge capacity of 66.7 mA h g-1at a current density of 40 mA g-1after 100 cycles. This will lay a solid foundation for the commercialization of aluminum-ion batteries. 2018 Journal Article http://hdl.handle.net/20.500.11937/73438 10.1021/acsami.8b00100 American Chemical Society restricted
spellingShingle Li, Z.
Niu, B.
Liu, Jian
Li, J.
Kang, F.
Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode
title Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode
title_full Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode
title_fullStr Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode
title_full_unstemmed Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode
title_short Rechargeable Aluminum-Ion Battery Based on MoS2Microsphere Cathode
title_sort rechargeable aluminum-ion battery based on mos2microsphere cathode
url http://hdl.handle.net/20.500.11937/73438