Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. A series of active-carbon-supported PdPb and PdCu bimetal catalysts were prepared for the selective semihydrogenation of alkynes in the liquid phase. The Pd0.33Pb0.67/C catalyst showed the best performance for various alkynes under mild reacti...
| Main Authors: | , , , , , |
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| Format: | Journal Article |
| Published: |
WILEY-V C H VERLAG GMBH,
2017
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| Online Access: | http://hdl.handle.net/20.500.11937/72701 |
| _version_ | 1848762820294868992 |
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| author | Liu, Jian Zhu, Y. Liu, C. Wang, X. Cao, C. Song, W. |
| author_facet | Liu, Jian Zhu, Y. Liu, C. Wang, X. Cao, C. Song, W. |
| author_sort | Liu, Jian |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. A series of active-carbon-supported PdPb and PdCu bimetal catalysts were prepared for the selective semihydrogenation of alkynes in the liquid phase. The Pd0.33Pb0.67/C catalyst showed the best performance for various alkynes under mild reaction conditions (room temperature and ambient H2pressure) and achieved 100 % conversion with 98 % selectivity to alkenes. In particular, over-hydrogenation was avoided at complete alkyne conversion. |
| first_indexed | 2025-11-14T10:53:38Z |
| format | Journal Article |
| id | curtin-20.500.11937-72701 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T10:53:38Z |
| publishDate | 2017 |
| publisher | WILEY-V C H VERLAG GMBH, |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-727012018-12-13T09:34:51Z Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts Liu, Jian Zhu, Y. Liu, C. Wang, X. Cao, C. Song, W. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. A series of active-carbon-supported PdPb and PdCu bimetal catalysts were prepared for the selective semihydrogenation of alkynes in the liquid phase. The Pd0.33Pb0.67/C catalyst showed the best performance for various alkynes under mild reaction conditions (room temperature and ambient H2pressure) and achieved 100 % conversion with 98 % selectivity to alkenes. In particular, over-hydrogenation was avoided at complete alkyne conversion. 2017 Journal Article http://hdl.handle.net/20.500.11937/72701 10.1002/cctc.201700800 WILEY-V C H VERLAG GMBH, restricted |
| spellingShingle | Liu, Jian Zhu, Y. Liu, C. Wang, X. Cao, C. Song, W. Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts |
| title | Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts |
| title_full | Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts |
| title_fullStr | Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts |
| title_full_unstemmed | Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts |
| title_short | Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts |
| title_sort | excellent selectivity with high conversion in the semihydrogenation of alkynes using palladium-based bimetallic catalysts |
| url | http://hdl.handle.net/20.500.11937/72701 |